Low temperature hot corrosion tests were performed on bulk Cr2AlC MAX phase compounds for the first time. This material is a known alumina-former with good oxidation and Type I high temperature hot corrosion resistance. Unlike traditional (Ni,Co)CrAl alumina-formers, it contains no Ni or Co that may react with Na2SO4 salt deposits needed to form corrosive mixed (Ni,Co)SO4-Na2SO4 eutectic salts active in Type II hot corrosion. Cr2AlC samples coated with 20K2SO4-80Na2SO4 salt were exposed to 300 ppm SO2 at 700°C for times up to 500 h. Weight change, recession, and cross-section microstructures identified some reactivity, but much reduced (< 1/10) compared to a Ni(Co) superalloy baseline material. Layered Al2O3/Cr2O3 scales were indicated, either separated by or intermixed with some retained salt. However, there was no conclusive indication of salt melting. Accelerated oxidation was proposed to explain the results, and coarse Cr7C3 impurities appeared to play a negative role. In contrast, the superalloy exhibited outer Ni(Co) oxide and inner Cr2O3 scales, with Cr-S layers at the interfaces. Massive spallation of the corrosion layers occurred repeatedly for the superalloy, but not at all for Cr2AlC. This indicates some potential for Cr2AlC as LTHC resistant coatings for superalloys.
1High-temperature corrosion fatigue, a combination of corrosion with a fatigue cycle, is an emerging generic issue affecting power generation and aero gas turbine engines and has the potential to limit component life. Historically, surface treatments, such as shot peening have been used to improve component life and have been optimised for fatigue response. Research into optimisation of shot peening techniques for hot corrosion and high-temperature corrosion fatigue has shown 6-8A 230H 200% coverage to provide overall optimum performance for nickel-based superalloy 720Li based on the limited data within this study. Utilisation of electron backscatter diffraction techniques, in combination with detailed assessment of corrosion products have been undertaken as part of this work. The resultant cold-work visualisation technique provides a novel method of determining the variation in material properties due to the shot peening process and the interaction with hot corrosion. Through this work it has been shown that all three shot peening outputs must be considered to minimise the effect of corrosion fatigue, the cold work, residual stress and surface roughness. Further opportunity for optimisation has also been identified based on this work.
The development of gas turbines to increase fuel efficiency is resulting in progressively higher operating temperatures in the under platform regions of the blades. These regions have traditionally been considered low risk areas. However, higher metal temperatures combined with stresses and the deposition of contaminants from the cooling air system may result in complex degradation mechanisms. Static stress corrosion testing has been conducted on C-ring specimens at a range of stresses in a hot corrosion environment. Cracks were observed in C-rings after exposure times greater than 100 h. Scanning electron microscopy (SEM) systems were used to image cracks and characterise deposits to improve understanding of the mechanism. Finite element analysis (FEA) has been used to model the stress intensity under test conditions. CMSX-4 specimens subject to static stresses combined with hot corrosion demonstrated significant material degradation (crack initiation and propagation) suggesting a combined stress corrosion mechanism resulting in cracking.
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