Owing to its unique thermodynamical description, phase separation has largely been modeled in the Cahn-Hilliard framework. In the present work, as a computationally efficient alternative, a multicomponent, multiphase-field model operating in Allen-Cahn framework is presented and subsequently employed to simulate spinodal decomposition. Stability analysis shows that the formulation can cover the effect of phase separation while simplifying the extension to multiple phases and incorporation of additional driving forces. Computational efficiency of the proposed approach is compared with the conventional technique by modeling intercalation in a representative one-dimensional domain. Moreover, intercalation within a multigrain system involving multiparticle interaction is studied. Our results suggest initiation of phase transformation at higher order junctions as well as a grain-by-grain intercalation behavior in a two-phase cathode material such as the well-studied LiFePO 4 .
A distributed Lagrange multiplier/fictitious domain method in a phase-field formulation for the simulation of rigid bodies in incompressible fluid flow is presented. The phase-field method yields an implicit representation of geometries and thus rigid body particulate flows within arbitrary geometries can be simulated based on a fixed Cartesian grid. Therefore, a phase-field based collision model is introduced in order to address contact of particles with arbitrary solid structures as boundaries. In addition, grain growth within the boundary geometry can be considered leading to changes in its shape during the simulation. The method is validated on benchmark problems and a convergence study is performed. Multiple numerical experiments are carried out in order to show the methods' capability to simulate problems with differently shaped rigid bodies and particulate flows involving complex boundary geometries like foam structures.
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