Semiconducting
quantum dots (QDs) engineering is considered as
an effective approach to improve the light-harvesting ability of the
devices for solar energy converting. Current routes for the construction
of QDs from metal–organic frameworks (MOFs) always retain carbon
materials to avoid particle aggregations, which could obstruct light
harvesting process. Herein, novel ZnCdS QDs without carbon supporting
are rationally designed and fabricated by controlled annealing and
a sequential sulfidation and ion-exchange procedure by a zeolitic-imidazolate-framework-8
(ZIF-8)-templated method. Notably, the quantum size could be well
controlled, and hence provide the ZnCdS QDs material with suitable
band matching, strong electron coupling, uniform and abundant active
sites, facilitated photoinduced charge kinetics, and shortened charge
diffusion distances, which are vital merits for enhancing photocatalytic
performance. The photocatalytic H2 production activity
of these QDs can be optimized through adjusting the quantum sizes.
Under the irradiation of visible-light and noble-metal cocatalyst-free,
an optimal H2 production rate of 3.70 mmol h–1 g–1 could be afford without using noble metal
cocatalysts, which is superior to those of bulk ZnCdS and most of
the reported ZnCdS-based catalysts. The facile and efficient approach
for ZnCdS QDs engineering could be extended to design other kinds
of highly efficient metal-sulfide QDs in advanced applications.
Non‐noble metal‐based bifunctional electrocatalysts are highly desired for water electrolysis. However, constructing a water electrolyzer using a sole catalyst without compromising either its oxygen evolution reaction (OER) or hydrogen evolution reaction (HER) performance is still challenging. In this study, a simple strategy is developed to integrate 2 D and 0 D CoP in the same metal–organic framework precursor‐derived hollow N‐doped carbon nanotube‐assembled polyhedron (HNCNP). The unique hierarchical structure endows the resulting nanocomposite with both the advantages of more exposed active sites for 2 D and large surface‐to‐volume ratio for 0 D materials, whereas the hollow interior could benefit the charge and mass transfer properties. Thus, CoP/HNCNP@2 D CoP exhibits outstanding OER and HER activity and a low cell voltage when employed as both the anode and cathode in a two‐electrode water electrolyzer. The approach of integrating the same metal phosphide phase with diverse dimensions may inspire new ways to design hierarchical nanostructures for advanced energy conversion applications.
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