Oil palm (Elaeis guineensis Jacq.) plantations in Indonesia are increasing over the past few years. After economic productivity, however, the unproductive oil palm trunks are felled and mostly go to waste, especially the inner part of the oil palm trunk (IOPT). There are several modification methods to utilize IOPT, such as impregnation and densification. Methylene diphenyl diisocyanate (MDI) is a common resin used for impregnation in composite industries because it is non-toxic and has excellent physical and mechanical properties but it has never been applied for the impregnation of IOPT. This study aimed to analyze the effect of densification on the physical and mechanical properties of the inner part of oil palm trunk (IOPT) impregnated using methylene diphenyl diisocyanate (MDI) resin to obtain valuable information regarding the efficient utilization of unproductive oil palm trunks. IOPT was densified and compregnated with compression ratios (CRs) of 20% and 30%. The physical properties (density, moisture content (MC), and water absorption (WA)) and mechanical properties (modulus of elasticity (MOE), modulus of rupture (MOR), and hardness) of the compregnated samples were better than those of the densified samples. The density and mechanical properties at CR 30% were higher than those at CR 20%. The improvements in density, MC, and WA of the compregnated IOPT with CR 30% were 127%, 54%, and 70%, respectively, compared to that in untreated IOPT. Furthermore, improvements in the MOE, MOR, and hardness of the compregnated IOPT with CR 30% were 489%, 379%, and 393%, respectively. The mechanical properties of the compregnated IOPT at CR 20% and 30% increased two- to three-fold from strength class V in control IOPT to strength class III in compregnated IOPT with CR 20% and to strength class II in compregnated IOPT with CR 30%, respectively.
Isocyanate impregnation was studied relative to the subterranean termite (Coptotermes curvignathus Holmgren) resistance of the inner part of oil palm (Elaeis guineensis Jacq.) trunk. Unproductive oil palm trunk was harvested and divided into top and bottom parts. Samples were isolated from the inner part of the trunk with a size of 2.5 cm x 2.5 cm x 0.5 cm. The samples were impregnated with 10% and 20% aqueous polymer-isocyanate and then heated at 60 °C for 48 h. The specimens were fed to subterranean termites under laboratory conditions. The weight percent gain values were 15.3% to 21.0% and 9.2% to 14.7% for the top and bottom parts, respectively. A higher isocyanate concentration decreased the moisture content and increased the density of inner part of the oil palm trunk. Impregnation with aqueous polymer-isocyanate increased termite mortality at the bottom part and decreased the feeding rate and weight percent loss. Impregnation with 10% and 20% aqueous polymer-isocyanate enhanced the resistance class of the bottom part of the inner part of the oil palm trunk from very poorly resistant (V) to poorly resistant (IV) and moderately resistant (III), respectively, based on the standard adopted.
Post-treatment of bamboo-oriented strand board (BOSB) through thermal modification can be an alternative to improve BOSB quality. This study aimed to analyze the effect of post-thermal treatment duration on the physical and mechanical properties of BOSB. Three-layers BOSB with a target density of 0.7 g/cm3 was made with the core layer perpendicular to the surface and bonded with 8% phenol-formaldehyde resin. The BOSB produced was then thermally-modified at 160°C for 1, 2, and 3 h. The physical and mechanical properties of BOSB were determined based on JIS A 5908-2003 standard. The results showed that the physical properties of the thermally-modified BOSB increased while the mechanical properties decreased compared to the untreated BOSB. The moisture content (MC), water absorption (WA), and thickness swelling (TS) of BOSB decreased with the increase in post-thermal treatment duration. The decrease in MC, WA, and TS of the thermally-modified BOSB reached 38.60%, 11.92%, and 33.26%, respectively. In addition, the decrease in modulus of elasticity (MOE), modulus of rupture (MOR), and internal bonding of the thermally-modified BOSB reached 19.18%, 23.15%, and 53.51%, respectively. The results showed that TS, MOE, and MOR of the thermally-modified BOSB still could meet the 0437.0 standards for commercial OSB (Grade O-1). Keywords: bamboo-oriented strand board, Dendrocalamus asper, physical and mechanical properties, post-thermal treatment, treatment duration
This research aimed to analyze the change in chemical composition of the betung bamboo (Dendrocalamus asper) strands after alkali immersion treatment under various immersion times. The bamboo culms were converted into strands with the target length, width, and thickness of 70, 25, and 0.5 mm, respectively. Strands were alkali immersion-treated with 1% NaOH solution for 1, 2, and 3 h. Preparation of powder for chemical component analysis refers to the Technical Association of the Pulp and Paper Industry (TAPPI) standard T 264 cm-07 regarding the preparation of wood test samples for chemical analysis. Structural and non-structural bamboo strand chemical components such as holocellulose, alpha-cellulose, hemicellulose, klason lignin, and extractives were analyzed. The results showed that alkali immersion treatment decreased the hemicellulose content from 21.55% before treatment to 20.30% after 3 h immersion. Thus, it changed the holocellulose and alpha-cellulose composition. Alkali immersion treatment also changed the extractive substances dissolved in cold water, hot water, 1% NaOH, and ethanol-benzene solution. The decrease in hemicellulose, molecular weight lignin, and extractive substances would be beneficial for bamboo-oriented strand board manufacture to improve strand adhesion, dimensional stability, mechanical properties, and durability against biological agents attack. Keywords: alkali immersion times, alkali immersion treatment, bamboo, chemical components, pre-treatment
Bamboos are often used due to their abundance, fast growth rate, cheap price, ductility, and formability in the sector of transportation, musical instrument, cooking ware, etc. For construction purposes, Dendrocalamus asper, (locally known as “Bambu betung”), is used as bamboo composites. The properties of bamboo are highly improved by using phenolic resins (phenol-formaldehyde) as an adhesive in bamboo composites. Bamboo is stronger and more susceptible to any liquid. The liquid is the most common enemy to plant-based structure due to the softening effect. Thus, the wettability of bamboo is an important matter as it indicates the ability of a liquid to spread and penetrate on the surface. The objective of this study was to analyze the effect of various heating times to wettability properties of heat-treated D. asper strands during the bamboo-composite making process. Before testing, the bamboo was cut, cleaned, and sand-grinded. The bamboo strands were heated at 140°C for 1, 2, and 3 hours. Then, the surface of bamboo was evaluated by measuring the contact angle based on the sessile drop method. The constant contact angle was obtained by calculating the regression formula between time (t) and contact angle (θ). The wettability was indicated by the value of K. The color of heat-treated bamboo strands was measured by portable color difference meter model CDX 105 and characterized by CIE Lab. The results showed that the longer the holding time, the surface became more hydrophobic, showed by a highercontact angle. Longer heating gives more time to the resin to spread more evenly into the pores of bamboo so that the hydrophobicity of bamboo composites is increased. The lightness value (L*) of heat-treated bamboo strands tended to decrease with increasing temperature and time of heat treatment. To conclude, for further making the process of bamboo composites using D. asper, we recommend curing the composites for 3 hours.
Oil palm trunk has become one of the waste that could damage the environment. Efforts that could be made to minimize the impact oil palm trunk’s existence were to turn the oil palm trunk into composite products. A composite product that could be made from palm oil trunks was blockboard. Oil palm trunk could be used as cores on block boards. Oil palm stems as raw material still have weaknesses. This weakness was the low dimensional stability due to hygroscopic properties. The treatment that could be done to increase dimensional stability while improving the adhesive quality was heat treatment. In this study, heat treatment of 140 °C and 160 °C for 1, 2, and 3 hours was carried out. The obtained results were 116.10°, 128.44°, and 133.52° for 1, 2, and 3 hours of treatment sequentially. The L* value in the heat-treated OPT tended to decrease, while the a* and b* values tended to increase compared to the control. The brightness level (L*) of the heat-treated OPT was more affected by temperature than the heat treatment time. Meanwhile, the a* and b* values were almost identical between treatments but differed from the controls. The total color change (?E) of the heat-treated OPT was not too large between treatments (moderate dark orange), but differed from the control (mostly desaturated dark orange).
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