Soot particles formed in a system of non-premixed liquid fuel flames supported on a wick-fed, smoke point test burner (ASTM D1322-08) were characterised by in-situ visible light extinction and thermophoretically-sampled high-resolution transmission electron microscopy measurements, HRTEM.
Reaction of 4-CN-PhOH with [ClP(μ-N(t)Bu)]2 (1) (2:1 ratio) in the presence of Et3N produced the functionalized cyclodiphosph(III/III)azane [(4-CN-PhO)P(μ-N(t)Bu)]2 (2). Oxidation of 2 produced cyclodiphosph(V/V)azanes [(4-CN-PhO)(E)P(μ-N(t)Bu)]2 [E = O (3), S (4), and Se (5)]. This is the first example of a series of cyclodiphosph(V/V)azane derivatives obtained from a single cyclophosph(III/III)azane precursor where all the accessible chalcogen oxidized products are air-stable over prolonged periods of time.
Recently, we have developed logical approaches to a family of phosphorus-nitrogen-based macrocycles of the type [{P(m-NR)} 2 (m-Y)] n . [1,2] The tetrameric, nitrogen-bridged macrocycle [{P(m-NtBu)} 2 (m-NH)] 4 (Scheme 1 a) is obtained by the condensation of the dimers [ClP(m-NtBu)] 2 and [(NH 2 )P-(m-NtBu)] 2 in the presence of Et 3 N.[3] However, the pentameric homologue is produced exclusively if this reaction is undertaken in the presence of I À ions, resulting in the hostguest complex [{P(m-NtBu)} 2 (m-NH)] 5 I À (Scheme 1 b).[4] The toroidal structures of the tetramer and pentamer and the presence of endo NÀH functionalities combine the appearance and host-guest characteristics of organic macrocycles such as calixarenes and porphyrins.Less progress has been made in attempts to extend this class of new ligands to macrocycles containing other bridging elements, owing largely to the inability to generalize the synthetic methods used for N-bridged species. Indeed, the only representative of this type reported to date is the oxygenbridged dimer [{P(m-N(2-py)} 2 (m-O)] 2 (2-py = 2-pyridyl), obtained by hydrolysis of [ClP{m-N(2-py)}] 2 in the presence of CuCl and pyridine.[5] However, we reported a key synthetic step in the potential extension of this methodology to a broader range of macrocycles by showing that oligomerization can be effected between P 2 N 2 units by the reaction of a deprotonated P(H) = O group with a P À Cl bond (Scheme 2). [6] This reaction can be rationalized by a change from a Pcentered to an O-centered nucleophile. In this sense, the reaction can be seen to involve an intermediate possessing "masked" functionality. However, it should be noted in this regard that the ambiguous nature of species containing [R 2 P = E] À anions (E = O, S, Se, NR, etc.) is well established by previous structural and theoretical studies, as is the fact that the negative charge normally lies primarily over to the side of E. [7] We report herein the success of this approach by showing that the reaction of the dimer [(Cl)(Se=)P(m-NtBu)] 2 (1) with excess sodium metal in toluene at reflux gives the macrocyclic, selenium-bridged hexamer [(Se = )P(m-NtBu) 2 P(m-Se)] 6 (2) as a crystalline product in good yield (45 %) by formal head-to-tail cyclization of the intermediate anion. The formation of the P-Se-P bridge again stems from the ambidentate nature of the intermediate anion (Scheme 3). Evidence of the resulting presence of alternate P III and P V centers within the backbone of 2 is seen in the roomtemperature 31 P{ 1 H} NMR spectrum in toluene, which shows P III (d, d = 206.8 ppm) and P V centers (d, d = 54.4 ppm) that are coupled to each other with a coupling constant that is typical of a P-(m-NR)-P bridge ( 2 J31 P-31 P = 44 Hz). [8] This spectrum can be compared to that of the precursor 1, which shows two singlet resonances in the P V region only, for the cis (d = 22.1 ppm, major) and trans (d = 22.7 ppm, minor) isomers (together with 77 Se satellites attributed to the AA'X isotopomer containing one 77 Se atom...
The hydrolysis of [ClP(mu-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [[[O-P(mu-NtBu)]2Li2]3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [O-P(mu-NtBu)]2(2-) dianion that is isoelectronic with ligands of the type [(RN)P(mu-NR)]2(2-).
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.