Abstract. An analysis of chemical composition data of particulate matter samples (TSP, PM 10 and PM 2.5 ) collected from 2002 to 2008 in the North Atlantic free troposphere at the Izaña Global Atmospheric Watch (GAW) observatory (Tenerife, Canary Islands) shows that desert dust is very frequently mixed with particulate pollutants in the Saharan Air Layer (SAL). The study of this data set with Median Concentrations At Receptor (MCAR) plots allowed the identification of the potential source regions of the dust and particulate pollutants. Areas located at the south of the southern slope of the Atlas mountains emerge as the most frequent source of the soil desert dust advected to the northern edge of the SAL in summer. Industrial emissions occurring in Northern Algeria, Eastern Algeria, Tunisia and the Atlantic coast of Morocco appear as the most important source of the nitrate, ammonium and a fraction of sulphate (at least 60 % of the sulphate <10 µm transported from some regions) observed in the SAL. These emissions are mostly linked to crude oil refineries, phosphate-based fertilizer industry and power plants. Although desert dust emissions appear as the most frequent source of the phosphorous observed in the SAL, high P concentrations are observed when the SAL is affected by emissions from open mines of phosphate and phosphate based fertilizer industry. The results also show that a significant fraction of the sulphate (up to 90 % of sulphate <10 µm transported from some regions) observed in the SAL may be influenced by soil emissions of evaporite minerals in well defined regions where dry saline lakes (chotts) are present. These interpretations of the MCAR plots are consistent with the results obtained with the Positive Matrix Factorization

Abstract. We have studied the relationship between the long-term interannual variability in large-scale meteorology in western North Africa – the largest and most active dust source worldwide – and Saharan dust export in summer, when enhanced dust mobilization in the hyper-arid Sahara results in maximum dust impacts throughout the North Atlantic. We address this issue by analyzing 28 years (1987–2014) of summer averaged dust concentrations at the high-altitude Izaña observatory (~ 2400 m a.s.l.) on Tenerife, and satellite and meteorological reanalysis data. The summer meteorological scenario in North Africa (aloft 850 hPa) is characterized by a high over the the subtropical Sahara and a low over the tropics linked to the monsoon. We measured the variability of this high–low dipole-like pattern in terms of the North African dipole intensity (NAFDI): the difference of geopotential height anomalies averaged over the subtropics (30–32° N, Morocco) and the tropics (10–13° N, Bamako region) close to the Atlantic coast (at 5–8° W). We focused on the 700 hPa standard level due to dust export off the coast of North Africa tending to occur between 1 and 5 km a.s.l. Variability in the NAFDI is associated with displacements of the North African anticyclone over the Sahara and this has implications for wind and dust export. The correlations we found between the 1987–2014 summer mean of NAFDI with dust at Izaña, satellite dust observations and meteorological re-analysis data indicate that increases in the NAFDI (i) result in higher wind speeds at the north of the Inter-Tropical Convergence Zone that are associated with enhanced dust export over the subtropical North Atlantic, (ii) influence the long-term variability of the size distribution of exported dust particles (increasing the load of coarse dust) and (iii) are associated with enhanced rains in the tropical and northern shifts of the tropical rain band that may affect the southern Sahel. Interannual variability in NAFDI is also connected to spatial distribution of dust over the North Atlantic; high NAFDI summers are associated with major dust export (linked to winds) in the subtropics and minor dust loads in the tropics (linked to higher rainfall), and vice versa. The evolution of the summer NAFDI values since 1950 to the present day shows connections to climatic variability (through the Sahelian drought, ENSO (El Niño–Southern Oscillation) and winds) that have implications for dust export paths. Efforts to anticipate how dust export may evolve in future decades will require a better understanding of how the large-scale meteorological systems represented by the NAFD will evolve.

Abstract. An analysis of the 22-yr ozone (O3) series (1988–2009) at the subtropical high mountain Izaña~station (IZO; 2373 m a.s.l.), representative of free troposphere (FT) conditions, is presented. Diurnal and seasonal O3 variations as well as the O3 trend (0.19 ± 0.05 % yr−1 or 0.09 ppbv yr−1), are assessed. A climatology of O3 transport pathways using backward trajectories shows that higher O3 values are associated with air masses travelling above 4 km altitude from North America and North Atlantic Ocean, while low O3 is transported from the Saharan continental boundary layer (CBL). O3 data have been compared with PM10, 210Pb, 7Be, potential vorticity (PV) and carbon monoxide (CO). A clear negative logarithmic relationship was observed between PM10 and surface O3 for all seasons. A similar relationship was found between O3 and 210Pb. The highest daily O3 values (90th percentile) are observed in spring and in the first half of summer time. A positive correlation between O3 and PV, and between O3 and 7Be is found throughout the year, indicating that relatively high surface O3 values at IZO originate from the middle and upper troposphere. We find a good correlation between O3 and CO in winter, supporting the hypothesis of long-range transport of photochemically generated O3 from North America. Aged air masses, in combination with sporadic inputs from the upper troposphere, are observed in spring, summer and autumn. In summer time high O3 values seem to be the result of stratosphere-to-troposphere (STT) exchange processes in regions neighbouring the Canary Islands. Since 1995–1996, the North Atlantic Oscillation has changed from a predominantly high positive phase to alternating between negative, neutral or positive phases. This change results in an increased flow of the westerlies in the mid-latitude and subtropical North Atlantic, thus favouring the transport of O3 and its precursors from North America, and a higher frequency of storms over North Atlantic, with a likely higher incidence of STT processes in mid-latitudes. These processes lead to an increase of tropospheric O3 in the subtropical North Atlantic region after 1996 that has been reflected in surface O3 records at IZO.