This paper studies the effects of the Mn-site substitution by nickel on the magnetic properties and the magnetocaloric properties of La 0.7 Ca 0.3 Mn 1-x Ni x O 3 (x = 0, 0.05 and 0.1). The orthorhombic crystal structures of the samples are confirmed by the room temperature X-ray diffraction. The dependence of the Curie temperature (T C ) and the magnetic entropy change (ΔS M ) on the Ni doping content was investigated. The samples with x = 0 had the first order phase transition, while the samples with x = 0.05 and 0.1 had the second order phase transition. As the concentration of Ni increased, the maximum entropy change (|ΔS M | max ) decreased gradually, from 2.78 J·kg
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