Polymer concrete (PC) has been used to replace cement concrete when harsh service conditions exist. Polymers have a high carbon footprint when considering their life cycle analysis, and with increased climate change concerns and the need to reduce greenhouse gas emission, bio-based polymers could be used as a sustainable alternative binder to produce PC. This paper examines the development and characterization of a novel bio-polymer concrete (BPC) using bio-based polyurethane used as the binder in lieu of cement, modified with benzoic acid and carboxyl-functionalized multi-walled carbon nanotubes (MWCNTs). The mechanical performance, durability, microstructure, and chemical properties of BPC are investigated. Moreover, the effect of the addition of benzoic acid and MWCNTs on the properties of BPC is studied. The new BPC shows relatively low density, appreciable compressive strength between 20–30 MPa, good tensile strength of 4 MPa, and excellent durability resistance against aggressive environments. The new BPC has a low carbon footprint, 50% lower than ordinary Portland cement concrete, and can provide a sustainable concrete alternative in infrastructural applications.
Rapid urbanization throughout the world resulted in a considerable amount of sewage sludge, which is commonly considered a great environmental concern. Also, the rapid growth of self-compacting concrete (SCC) marks a significant milestone in enhancing the construction industry's effectiveness. Hence, an experimental program was carried out to study self-compacting concrete (SCC) properties incorporating sewage sludge ash (SSA) as a partial replacement of cement. Mixes were prepared with two percentages (0 and 20% by mass) of SSA as partial replacement of cement. The slump flow, T50 flow time, J-ring, and V-funnel were evaluated for the fresh SCC. Hardened properties of SCC were assessed by measuring compressive strength, rapid chloride penetration, bulk electrical resistivity, water absorption rate (i.e., sorptivity), and water permeability. Test results indicated that SCC made with SSA must incorporate a higher dosage of admixtures than the control mix to achieve satisfactory workability, passing ability, and viscosity. SSA contributed to the concrete mix's late strength development and led to durable concrete with a low chloride permeability resistance and a high electrical resistivity. There was a negligible increase in the rate of water absorption and water permeability. However, the water absorption rate and permeability are expected to reduce with age due to the pozzolanic reaction of SSA. SSA was found to have the potential to be used as partial cement replacement in making SCC, which could lead to a profound impact on solid waste management and sustainable development in the construction industry.
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