Membrane technology has emerged as a leading tool worldwide for effective CO 2 separation because of its well-known advantages, including high surface area, compact design, ease of maintenance, environmentally friendly nature, and costeffectiveness. Polymeric and inorganic membranes are generally utilized for the separation of gas mixtures. The mixed-matrix membrane (MMM) utilizes the advantages of both polymeric and inorganic membranes to surpass the trade-off limits. The high permeability and selectivity of MMMs by incorporating different types of fillers exhibit the best performance for CO 2 separation from natural gas and other flue gases. The recent progress made in the field of MMMs having different types of fillers is emphasized. Specifically, CO 2 /CH 4 and CO 2 /N 2 separation from various types of MMMs are comprehensively reviewed that are closely relevant to natural gas purification and compositional flue gas treatment

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CO2 emission from anthropogenic sources has raised worldwide environmental concerns and hence proficient energy paradigm has tilted towards CO2 capture. Membrane technology is one of the efficient technologies for CO2 separation since it is environmentally friendly, inexpensive, and offers high surface areas. Various approaches are discussed to improve membrane performance focusing mainly on permeability and selectivity parameters. Different types of fillers are incorporated to reach the Robeson's upper bound curve. In this review, polymer‐inorganic nanocomposite membranes for the separation of CO2, CH4, and N2 from various gas mixtures are comprehensively discussed. Metal organic frameworks (MOFs) and ionic liquid (ILs) mixed‐matrix membranes are also considered.

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