A pendant drop merging with a sessile drop and subsequently forming a single daughter drop, is known to exhibit complex topologies, but their dynamics are yet to be probed for...

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We investigate electroosmotic flow of two immiscible viscoelastic fluids in a parallel plate microchannel. Contrary to traditional analysis, the effect of the depletion layer is incorporated near the walls, thereby capturing the complex coupling between rheology and electrokinetics. Toward ensuring realistic prediction, we show the dependence of electroosmotic flow rate on the solution pH and polymer concentration of the complex fluid. In order to assess our theoretical predictions, we have further performed experiments on electroosmosis of an aqueous solution of polyacrylamide (PAAm). Our analysis reveals that neglecting the existence of a depletion layer would result in grossly incorrect predictions of the electroosmotic transport of such fluids. These findings are likely to be of importance in understanding electroosmotically driven transport of complex fluids, including biological fluids, in confined microfluidic environments.

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SynopsisTwo-component interpenetrating polymer metworks (IPN) of the SIN type (simultaneous interpenetrating networks) were prepared from three different polyurethanes and two epoxies. The linear prepolymers were combined in solution, together with crosslinking agents and catalysts, films cast, and subsequently chain extended and crosslinked in situ. Two of the IPN's showed significant improvement in thermal resistance, as measured by thermogravimetric analysis (TGA). All of the IPN's showed maxima in tensile strength significantly higher than the tensile strengths of the component networks at 25% polyurethane and minima at 75y0 polyurethane. The minima were explained by an initial dilution of the strong polyurethane hydrogen bonds by the epoxies, and the maxima, by an increase in crosslink density due to interpenetration.

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