Abstract. One of the most important processes in the global mercury (Hg) biogeochemical cycling is the deposition of atmospheric Hg, including gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate-bound mercury (PBM), to the land surfaces. Results of wet, dry, and forest Hg deposition from global observation networks, individual monitoring studies, and observation-based simulations have been reviewed in this study. Uncertainties in the observation and simulation of global speciated atmospheric Hg deposition to the land surfaces have been systemically estimated based on assessment of commonly used observation methods, campaign results for comparison of different methods, model evaluation with observation data, and sensitivity analysis for model parameterization. The uncertainties of GOM and PBM dry deposition measurements come from the interference of unwanted Hg forms or incomplete capture of targeted Hg forms, while that of GEM dry deposition observation originates from the lack of a standardized experimental system and operating procedure. The large biases in the measurements of GOM and PBM concentrations and the high sensitivities of key parameters in resistance models lead to high uncertainties in GOM and PBM dry deposition simulation. Non-precipitation Hg wet deposition could play a crucial role in alpine and coastal regions, and its high uncertainties in both observation and simulation affect the overall uncertainties of Hg wet deposition. The overall uncertainties in the observation and simulation of the total global Hg deposition were estimated to be ± (25–50) % and ± (45–70) %, respectively, with the largest contributions from dry deposition. According to the results from uncertainty analysis, future research needs were recommended, among which a global Hg dry deposition network, unified methods for GOM and PBM dry deposition measurements, quantitative methods for GOM speciation, campaigns for comprehensive forest Hg behavior, and more efforts in long-term Hg deposition monitoring in Asia are the top priorities.

Nonferrous metal smelting (NFMS) is one of the key sources of mercury (Hg) emissions to the air and cross-media Hg transfer in China. In this study, a "Hg removal compensation effect" between upstream and downstream air pollution control devices (APCDs) in NFMS was uncovered based on the investigation of field test data. The relationships between the Hg concentration in flue gas and the Hg removal efficiencies of typical APCDs were established, and an advanced probabilistic mass flow model regarding this effect was developed. Model comparison shows that the probabilistic essence of the advanced model prevents the underestimation of the deterministic model caused by using the geometric means of the Hg contents of metal concentrates, and the consideration of the removal compensation effect leads to more accurate estimation of the overall Hg removal efficiency of cascaded APCDs. The Hg emission abatement in the NFMS sector from 2010 to 2017 was evaluated to be 55.6 t, which was 13.5% higher than the estimate without considering the Hg removal compensation effect. The overall uncertainty of the improved model was reduced. This study provides a new methodology for more accurate evaluation of the effectiveness of the national implementation plan for the Minamata Convention on Mercury.

<p><strong>Abstract.</strong> One of the most important processes in the global mercury biogeochemical cycling is the deposition of atmospheric mercury, including gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate-bound mercury (PBM), to terrestrial surfaces. In this paper, methods for the observation of wet, dry, litterfall, throughfall, and cloud/fog deposition and models for mercury dry deposition are reviewed. Surrogate surface methods with cation exchange membranes are widely used for GOM dry deposition measurements, while observation methods for GEM dry deposition are more diverse. The methodology for Hg wet deposition is more mature, but the influence of cloud/fog scavenging is easy to neglect. Dry deposition models for speciated mercury have high uncertainties owing to the presence of sensitive parameters related to GOM chemical forms. Observation networks for mercury wet deposition have been developed worldwide, with the Global Mercury Observation System (GMOS) covering the northern hemisphere, the tropics, and the southern hemisphere. Wet deposition implies the spatial distribution of atmospheric mercury pollution, while GOM dry deposition depends highly on the elevation. Litterfall Hg deposition is crucial to forests. Urban areas have high wet deposition and PBM dry deposition because of high reactive mercury levels. Grasslands and forests have significant GOM and GEM dry deposition, respectively. Evergreen broadleaf forests bear high litterfall Hg deposition. Future research needs have been proposed based on the current knowledge of global mercury deposition to terrestrial surfaces.</p>