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With the increasing demand for high-quality steel, the requirements for the efficiency and stability of deep desulfurization are increasing too. The Kanbara Reactor (KR) is widely accepted around the world because of its high efficiency and economy. In order to destroy the rigid motion of molten iron in this area, two kinds of blade structures are designed and compared with traditional blades. In this study, a three-dimensional transient coupling mathematical model was established by using volume of fluid (VOF) and discrete phase model (DPM) to simulate the KR desulfurization process. The turbulence intensity of the molten iron, main vortex size and desulfurizing agent (DA) particle distributions for the three impeller models were investigated in detail. Model results showed that the staggered blade structure may improve the desulfurization efficiency of the KR process, and the desulfurization rate increases from 95.7% to 97.1% when compared with ordinary blades. The main reason for this can be attributed to the enhanced turbulence intensity of the molten iron, larger main vortex size and more uniform DA particle distributions. Plant tests also showed that the desulfurizer consumption per 1 ppm sulfur for the staggered blades was reduced by approximately 8.6%.