All-polymer organic solar cells offer exceptional stability. Unfortunately, the use of bulk heterojunction (BHJ) structure has the intrinsic challenge to control the side-chain entanglement and backbone orientation to achieve sophisticated phase separation in all-polymer blend. Here, we revealed that the P-iN structure can outperform the BHJ ones with a nearly 50% efficiency improvement, reaching a power conversion efficiency approaching 10%. This P-iN structure can also provide enhanced internal electric field and remarkably stable morphology under harsh thermal stress. We have further demonstrated generality of the P-iN structure in several other all-polymer systems. Considering the adjustable polymer molecular weight and solubility, the PiN device structure can be more beneficial for all-polymer systems. With the design of more crystalline polymers, the antiquated P-iN structure can further show its strength in all-polymer system by simplified morphology control and improved carrier extraction, becoming a more favorite device structure than dominant BHJ structure.

Organic solar cells (OSCs) based on small molecular acceptors (SMAs) have made great development with a power conversion efficiency (PCE) over 16% due to the design of novel materials and advances in device preparation technology. This work fabricates two bulk‐heterojunction photovoltaic devices containing the same wide‐bandgap donor PM6, respectively, matched with popular Y6 and ITIC SMAs. The PM6:Y6‐based device achieves a much higher PCE of 15.21% than the PM6:ITIC‐based device of 9.02%. On the basis of comparisons of macroscopic performances in the quasistatic regime, transient absorption spectroscopy (TAS) is further performed to better understand the microscopic dynamics difference in charge separation processes between the two photovoltaic blends. According to the TAS results, the calculated hole transfer efficiency in PM6:Y6 is 71.4%, far greater than the efficiency of 13.1% in PM6:ITIC, demonstrating favorable charge separation at donor/acceptor interfaces via hole transfer channel in PM6:Y6. The favorable hole transfer in PM6:Y6 is accounted for by its better mutual miscibility between the donor and acceptor, and the formation of long‐lived delocalized intramoiety excimer state in the acceptor. These results highlight the important role of proper molecular design strategy with strong intermolecular coupling and beneficial film morphology on facilitating charge generation in OSCs adopting SMAs.

We report an ultrafast optical switching device constructed by stacking two layers of gold nanowires into a perpendicularly crossed network, which works at a speed faster than 280 fs with an on/off modulation depth of about 22.4%. The two stacks play different roles in enhancing consistently the optical switching performance due to their different dependence on the polarization of optical electric fields. The cross-plasmon resonance based on the interaction between the perpendicularly stacked gold nanowires and its Fano-coupling with Rayleigh anomaly is the dominant mechanism for such a high-contrast optical switching device.

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Simultaneous distributed feedback (DFB) lasing and linear polarized random lasing are observed in a compound cavity, which consists of a grating cavity and a random cavity. The grating cavity is fabricated by interference lithography. A light-emitting polymer doped with silver nanoparticles is spin-coated on the grating, forming a random cavity. DFB lasing and random lasing occur when the periodic-random compound cavity is optically pumped. The directionality and polarization of the random laser are modified by the grating structure. These results can potentially be used to design integrated laser sources.