An asymmetric α-C–H alkenylation of aryl alkenes has been disclosed to provide axially chiral aryl 1,3-dienes, proceeding through six-membered exo-cyclopalladation, assisted by an aldehyde/l-t-leucine derived transient chiral auxiliary.
We present a Pd-catalyzed atroposelective preparation of aryl 1,3-dienes from readily available styrenes and olefins through aldehyde derived transient chiral auxiliary, proceeding by enantioselective olefinic C-H alkenylation of styrenes via...
We report on N,N-bidentate-chelation-assisted α- and β-olefinic C-H alkenylation of aryl alkenes in ethanol to afford aryl dienes/trienes with excellent regio- and stereo-selectivities. The reaction of 2-alkenyl benzylamine and benzoic...
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