X-ray fluorescence (XRF) spectroscopy offers a fast and efficient method for analysing soil elemental composition, both in the laboratory and the field. However, the technique is sensitive to spectral interference as well as physical and chemical matrix effects, which can reduce the precision of the measurements. We systematically assessed the XRF technique under different sample preparations, water contents, and excitation times. Four different soil samples were used as blocks in a three-way factorial experiment, with three sample preparations (natural aggregates, ground to ≤2 mm and ≤1 mm), three gravimetric water contents (air-dry, 10% and 20%), and three excitation times (15, 30 and 60 s). The XRF spectra were recorded and gave 540 spectra in all. Elemental peaks for Si, K, Ca, Ti, Fe and Cu were identified for analysis. We used analysis of variance (anova) with post hoc tests to identify significant differences between our factors and used the intensity and area of the elemental peaks as the response. Our results indicate that all of these factors significantly affect the XRF spectrum, but longer excitation times appear to be more defined. In most cases, no significant difference was found between air-dry and 10% water content. Moisture has no apparent effect on coarse samples unless ground to 1 mm. We suggested that the XRF measurements that take 60 s from dry samples or only slightly moist ones might be an optimum option under field conditions.
Soil salinization is one of the major degradation processes threatening food security and sustainable development. Detailed soil salinity information is increasingly needed to tackle this global challenge for improving soil management. Soil-visible and near-infrared (Vis-NIR) spectroscopy has been proven to be a potential solution for estimating soil-salinity-related information (i.e., electrical conductivity, EC) rapidly and cost-effectively. However, previous studies were mainly conducted at the field, regional, or national scale, so the potential application of Vis-NIR spectroscopy at a global scale needs further investigation. Based on an extensive open global soil spectral library (61,486 samples with both EC and Vis-NIR spectra), we compared four spectral predictive models (PLSR, Cubist, Random Forests, and XGBoost) in estimating EC. Our results indicated that XGBoost had the best model performance (R2 of 0.59, RMSE of 1.96 dS m−1) in predicting EC at a global scale, whereas PLSR had a relatively limited ability (R2 of 0.39, RMSE of 2.41 dS m−1). The results also showed that auxiliary environmental covariates (i.e., coordinates, elevation, climatic variables) could greatly improve EC prediction accuracy by the four models, and the XGBoost performed best (R2 of 0.71, RMSE of 1.65 dS m−1). The outcomes of this study provide a valuable reference for improving broad-scale soil salinity prediction by the coupling of the spectroscopic technique and easily obtainable environmental covariates.
Measuring the soil salinity using visible and near-infrared (vis–NIR) reflectance spectra is considered a fast and cost-effective method. For monitoring purposes, estimating soils with low salinity measured as electrical conductivity (EC) using vis–NIR spectra is still understudied. In this research, 399 legacy soil samples from six regions of Southern Xinjiang, China with low EC values were used. Reflectance spectra were measured in the laboratory on dried and ground soil samples using a portable vis–NIR spectrometer. By using 10-fold cross-validation, three algorithms–partial least-squares regression (PLSR), random forest (RF), and Cubist–were employed to develop statistical models of EC. The model performance evaluation was obtained by the relative importance of variants. In terms of accuracy assessment of soil EC prediction, the results demonstrated that the Cubist model performed better (R2 = 0.67, RMSE = 0.16 mS/cm, RPIQ = 2.28) than both PLSR and RF. Despite similar variants for modelling, the RF model performed somewhat better than that of the PLSR. Additionally, the 610 nm and 790 nm wavelengths only demonstrated significant promise for predicting low soil EC values when used in the Cubist mode. The current research recommends the use of Cubist to estimate the low soil salinity using the vis–NIR reflectance spectra.
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