In this article, Co-based metal organic frameworks (MOFs) with two shapes were used as pyrolysis precursor to synthesize multilayer core-shells composites loaded on reduced graphene oxide (rGO) sheets. The core-shell structures were obtained by the formation of cores from metal ions and carbon shells from carbonization of ligands. Controllable oxidation of Co cores to CoOx shells generated multilayer core-shell structures anchored onto the surface of rGO sheets. The N-doped composites were obtained by adding poly vinylpyrrolidone. The multilayer core-shells composites exhibited superior catalytic activity toward hydrogen generation compared to their single layer counterparts. By using the N-doped multilayer composites, high hydrogen generation specific rate of 5560 mL min(-1) gCo(-1) was achieved at room temperature. The rGO sheets in composites improved their structure stability. These catalysts exhibited high stability after used five cycling. This synergistic strategy proposes simple, efficient, and versatile blue-prints for the fabrication of rGO composites from MOFs-based precursors.

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Magnetic CoFe2O4/rGO nanocomposites were fabricated via a solvothermal process and used as environmentally-friendly adsorbents for the adsorption of organic dyes.

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BackgroundClonorchiasis, caused by Clonorchis sinensis (C. sinensis) infection, is a serious food-borne zoonotic disease that is often asymptomatic or shows only mild symptoms, which leads to delayed treatment and chronic clonorchiasis and results in various complications, such as cholelithiasis, cholangitis, cholecystitis and cholangiocarcinoma. However, acute shock caused by C. sinensis infection has not been reported. Here, for the first time, we describe a fatal case of acute shock caused by C. sinensis infection.Case presentationA patient with a history of eating raw or undercooked freshwater fish was hospitalized with acute shock caused by severe abdominal pain. Physical examination suggested acute abdomen with severe abdominal pain and rigidity. Computed tomography (CT) detection indicated acute cholecystitis and cholelithiasis. After cholecystectomy, several liver flukes were found in the drainage tube. Furthermore, morphological analysis and polymerase chain reaction (PCR) identified the pathogen as C. sinensis. The liver gradually restored normal function after anthelmintic therapy with praziquantel.ConclusionsIn this fatal case, C. sinensis infection was the cause of acute shock, which is rarely found in the clinic environment. This report aims to increase awareness of the hazards and complications related to clonorchiasis. The PCR diagnosis method used in this report might be helpful in reducing the misdiagnosis of clonorchiasis and unnecessary cholecystectomy.

PurposeThe selection of purchasing channels by wine consumers indirectly affects buying experience and satisfaction, therefore, it is of great practical significance to study consumers' preference on channel selection. The purpose of this study is to investigate the current state of consumer selection for purchasing channel and the corresponding influencing factors.Design/methodology/approachA total of 2,976 valid questionnaires were collected by convenience sampling from 34 provinces, municipalities and autonomous regions of China in 2020 via the Internet, yielding a response rate of 82.2%. A categorical statistical approach was used to understand consumer's selection for each channel. Besides, binary logistic regression model was used to analyze the factors affecting consumers' channel selection.FindingsThe results show that Chinese wine consumers' main purchasing channels are as follows: supermarket/mall, wine specialty stores, comprehensive e-business flagship stores, comprehensive e-business individual stores, restaurants and short video and live streaming platforms. Estimation results showed that among the 12 influencing factors in 4 categories, consumers' education and some other factors significantly influenced consumers' decision on wine purchasing channels.Research limitations/implicationsLimited by time and experimental conditions, this study did not analyze the trend of wine consumers' purchasing channel selection. Future work would concentrate on multi-year data and conduct longitudinal comparative analysis.Originality/valueThis study innovatively subdivides the currently popular wine sales channels in Chinese market and conducts research related to consumer channel selection. The results of the study can provide reference for wine producers and distributors to update their strategic layout and also help various channels to understand the characteristics of their customer groups for targeted marketing.

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