Multiferroic CoFe(2)O(4)-Pb(Zr(0.52)Ti(0.48))O(3) core-shell nanofibers have been synthesized by coaxial electrospinning in combination with a sol-gel process. The core-shell configuration of nanofibers has been verified by scanning electron microscopy and transmission electron microscopy, and the spinel structure of CoFe(2)O(4) and perovskite structure of Pb(Zr(0.52)Ti(0.48))O(3) have been confirmed by X-ray diffraction and selected area electron diffraction. The multiferroic properties of core-shell nanofibers have been demonstrated by magnetic hysteresis and piezoresponse force microscopy, and their magnetoelectric coupling has been confirmed by evolution of piezoresponse under an external magnetic field, showing magnetically induced ferroelectric domain switching and changes in switching characteristics. The lateral magnetoelectric coefficient is estimated to be 2.95 × 10(4) mV/cmOe, two orders of magnitude higher than multiferroic thin films of similar composition.
The p-type BiCuOCh (Ch ¼ S, Se and Te) compounds exhibit very low lattice thermal conductivities and moderate power factors in the medium temperature range, resulting in high thermoelectric figures of merit. In this paper, we investigated their electronic structures using density functional theory, and discovered that a mixture of heavy and light bands near the valence band maximum is beneficial for good thermoelectric performance, and the Cu 3d-Ch np antibonding state near the valence band edge determines the transport properties of BiCuOCh. Semi-classic Boltzmann transport theory was then used to calculate the Seebeck coefficients, electrical conductivities and power factors of BiCuOCh, and the optimal doping concentrations were estimated based on the predicted maximum power factors. The temperature dependence of the thermoelectric transport properties of BiCuOSe were also estimated and compared with experimental data, with good agreement observed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.