Pure and Na(+) -doped Alq3 complexes were synthesized by a simple precipitation method at room temperature, maintaining a stoichiometric ratio. These complexes were characterized by X-ray diffraction, Fourier transform infrared (FTIR), UV/Vis absorption and photoluminescence (PL) spectra. The X-ray diffractogram exhibits well-resolved peaks, revealing the crystalline nature of the synthesized complexes, FTIR confirms the molecular structure and the completion of quinoline ring formation in the metal complex. UV/Vis absorption and PL spectra of sodium-doped Alq3 complexes exhibit high emission intensity in comparison with Alq3 phosphor, proving that when doped in Alq3 , Na(+) enhances PL emission intensity. The excitation spectra of the synthesized complexes lie in the range 242-457 nm when weak shoulders are also considered. Because the sharp excitation peak falls in the blue region of visible radiation, the complexes can be employed for blue chip excitation. The emission wavelength of all the synthesized complexes lies in the bluish green/green region ranging between 485 and 531 nm. The intensity of the emission wavelength was found to be elevated when Na(+) is doped into Alq3 . Because both the excitation and emission wavelengths fall in the visible region of electromagnetic radiation, these phosphors can also be employed to improve the power conversion efficiency of photovoltaic cells by using the solar spectral conversion principle. Thus, the synthesized phosphors can be used as bluish green/green light-emitting phosphors for organic light-emitting diodes, flat panel displays, solid-state lighting technology - a step towards the desire to reduce energy consumption and generate pollution free light.
We present an extension of our search for 'Extremely Inverted Spectrum Extragalactic Radio Sources' (EISERS) to the northern celestial hemisphere. With an inverted radio spectrum of slope α > +2.5, these rare sources would either require a non-standard particle acceleration mechanism (in the framework of synchrotron self-absorption hypothesis), or a severe free-free absorption which attenuates practically all of their synchrotron radiation at metre wavelengths. By applying a sequence of selection filters, a list of 15 EISERS candidates is extracted out by comparing two large-sky radio surveys, WENSS (325 MHz) and TGSS-ADR1 (150 MHz), which overlap across 1.03π steradian of the sky. Here we report quasi-simultaneous GMRT observations of these 15 EISERS candidates at 150 MHz and 325 MHz, in an attempt to accurately define their spectra below the turnover frequency. Out of the 15 candidates observed, two are confirmed as EISERS, since the slope of the inverted spectrum between these two frequencies is found to be significantly larger than the critical value α c = +2.5: the theoretical limit for the standard case of synchrotron self-absorption (SSA). For another 3 sources, the spectral slope is close to, or just above the critical value α c . Nine of the sources have GPS type radio spectra. The parsec-scale radio structural information available for the sample is also summarised.A few years ago, we combined the TIFR GMRT SKY SURVEY (TGSS/DR5) at 150 MHz with the 352 MHz WISH survey, to search for extragalactic radio sources whose
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