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The photoluminescence intensity of ZnS-AgInS(2) solid solution nanoparticles was remarkably enhanced by increasing the heating temperature to 180 degrees C, above which the emission was simply diminished, while ZnS coating of the particles resulted in further enhancement of PL intensity, giving the highest quantum yield of ca. 80%.

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We present the results of a systematic, broadband X-ray spectral analysis of nearby active galactic nuclei (AGNs) with the X-ray clumpy torus model (XCLUMPY). By adding 16 AGNs newly analyzed in this paper, we study a total of 28 AGNs, including unabsorbed and absorbed AGNs taken from Ichikawa et al. and García-Bernete et al. This is the largest sample whose X-ray and infrared spectra are analyzed by the clumpy torus models XCLUMPY and CLUMPY, respectively. The relation between the Eddington ratio and the torus covering factor determined from the X-ray torus parameters of each object follows the trend found by Ricci et al. based on a statistical analysis. We confirm the results by Tanimoto et al. that (1) the torus angular widths determined by the infrared data are larger than those by the X-ray data and (2) the ratios of hydrogen column density to V-band extinction (N H/A V ) along the line of sight in obscured AGNs are similar to the Galactic value, on average. Unobscured AGNs show apparently smaller line-of-sight N H/A V ratios than the Galactic one. Our findings can be well explained by an updated unified picture of AGN structure including a dusty torus, dusty polar outflows, and dust-free gas, where the inclination determines the X-ray and optical classifications and observed torus properties in the X-ray and infrared bands.

We apply XCLUMPY, an X-ray spectral model from a clumpy torus in an active galactic nucleus (AGN), to the broadband X-ray spectra of 10 obscured AGNs observed with both Suzaku and NuSTAR. The infrared spectra of these AGNs were analyzed by Ichikawa et al. with the CLUMPY code. Because XCLUMPY adopts the same clump distribution as that in the CLUMPY, we can directly compare the torus parameters obtained from the X-ray spectra and those from the infrared spectra. The torus angular widths determined from the infrared spectra (σ IR) are systematically larger than those from the X-ray data (σ X); the difference ( ) correlates with the inclination angle determined from the X-ray spectrum. These results can be explained by the contribution from dusty polar outflows to the observed infrared flux, which becomes more significant at higher inclinations (more edge-on views). The ratio of the hydrogen column density to the V-band extinction in the line-of-sight absorber shows a large scatter (≃1 dex) around the Galactic value, suggesting that a significant fraction of AGNs have dust-rich circumnuclear environments.