It is important to match the feeding ratio of comonomers to the composition ratio in the resulting copolymers as closely as possible in industrial production, where the goal is often to produce more a homogeneous composition in copolymers. In this study, a flow copolymerization system with a conventionally initiated free radical method, together with randomly selected polymerization conditions is investigated. It is succeeded in achieving a closer match between the composition ratio and feeding ratio than previously reported in the copolymerization of styrene with methyl methacrylate and of glycidyl methacrylate with methyl methacrylate, which will widen the range of applications, by precisely controlling the mixing and heating in a flow polymerization apparatus. This is confirmed by the fact that the estimated values of reactivity ratios, r 1 and r 2 , which are used in the reaction kinetics of copolymerization, are close to 1.
The properties of polymers are highly dependent on the combination and composition ratio of the monomers used to prepare them; however, the large number of available monomers makes an exhaustive...
The effect of the amount of 2,2′-Bis(2-oxazoline) on the spectral, thermal, morphological, and tensile properties of polypropylene (PP)/liquid crystalline polymer (LCP)/maleic anhydride grafted PP (PP-g-MAH) blends was investigated. A wholly aromatic LCP having a low melting point, namely a AL-7000 copolyester was used, because it also uses a compatibilizer with a low decomposition temperature. As the amount of 2,2′-Bis(2-oxazoline) increased, the dispersibility of the LCP improved and the tensile properties were improved, but when it was added in excess, a loss in function was observed. In particular, when 0.5 wt% of 2,2′-Bis(2-oxazoline) were added, the tensile strength and elastic modulus were the highest, and cohesive fracture (fracture within the matrix, not at the PP/LCP interface) was observed in the scanning electron microscope image.
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