The ribbons with different thicknesses of Fe83Ga17 alloy were prepared by melt spun. The maximum magnetostriction of −2100ppm has been obtained in the ribbon with the thickness of 75μm. The microstructures of the ribbons were determined by x-ray diffraction. It was found that DO3 structure emerges in those ribbons melt spun at a higher cooling rate. This special DO3 structure is favorable to the enhancement of magnetostriction. It is considered that more short-range ordering of Ga atoms appeared when liquid alloy was solidified with a certain extreme cooling rate. Such short-range ordering of Ga atoms brings a local stress and results in the giant magnetostriction. The large demagnetizing magnetic energy in the normal direction of the ribbons causes the magnetic moments parallel to the ribbon plane. When an applied magnetic field is perpendicular to the ribbon plane, the magnetic moments turn 90° and generate giant magnetostriction.

Phase transformations and magnetic properties of overquenched Pr7Fe88B5 ribbons during annealing have been investigated. X-ray diffraction and Mössbauer measurement indicate that melt spinning at different wheel velocities caused the as-quenched ribbons to have distinctive structures. Depending on their as-quenched structure, the phase transformation of the ribbons during annealing may take place in one of the following sequences: (1) amorphous phase (Am)+Pr2Fe14B+α-Fe→Pr2Fe14B+α-Fe; (2) Am+α-Fe→Am′+α-Fe→α-Fe+1:7 phase+Pr2Fe14B→Pr2Fe14B+α-Fe; and (3) Am→Am′+α-Fe→1:7 phase+α-Fe→Pr2Fe14B+α-Fe. In all cases, the microstructure of the ribbons after optimal annealing was found to only consist of two magnetic phases: Pr2Fe14B and α-Fe. However, with increasing initial quenching rate, the microstructure of optimally heat treated ribbons becomes coarser and more irregular, and the magnetic properties of them deteriorated drastically. The δM plots, irreversible susceptibility, and the temperature dependence of coercivity of the annealed ribbons were measured and analyzed. It was found that the coarser-grained and more irregular microstructures, as mentioned above, would lead to the weakening of the exchange coupling effect between the hard and soft phase, the inhomogeneous nucleation of reverse domain, a lower critical nucleation field, and a decrease in αex and Neff. These may be the reasons that the optimal magnetic properties of annealed ribbons reduce significantly with increasing initial quenching rate.

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