Composite electrolytes (CE) combining a ceramic filler and a polymer matrix is an effective way to enhance battery safety. But the increased ceramic filler mass fraction decreases the flexibility, which increases the interfacial resistance. To alleviate interfacial resistance further, a gradient composite electrolyte (GCE) using a Sc, Ge-doped Na 3 Zr 2 Si 2 PO 12 (NZSP) as the ceramic filler and poly(ethylene oxide) (PEO) as the polymer matrix is proposed. The outer layer contains a low concentration of ceramic filler to improve interfacial contact, and the central layer contains a high concentration of ceramic filler to inhibit dendrite penetration. This GCE possesses an enhanced conductivity (4.0 × 10 −5 S cm −1 at 30 °C) and a reduced interfacial resistance. Furthermore, the safety was boosted using Sn 4 P 3 @CNT/C as the high-capacity anode active material and Na 3 V 2 (PO 4 ) 3 (NVP) as the cathode active material. This ultrasafe sodium metal-free, solid-state sodium-ion battery (SSSIB) displays an impressive cycling performance.
Sn‐based lithium‐ion battery anodes show improved capacities over commercial carbon‐based anodes. Furthermore, their higher lithiation potentials reduce the risks of Li dendrite formation. A simple Cu6Sn5 fabrication method has been previously demonstrated, but the resultant anode shows a poor reversible capacity of 470 mAh g–1. This study investigates the effects of Co in modifying the microstructure, crystal structure and electrochemical properties of Cu6Sn5 to improve the electrochemical performances of the electrode. Significant enhancement in the electrochemical properties were obtained in the Co‐doped Cu6Sn5 electrodes, where a cycling capacity as high as 830 mAh g–1 was observed during the early cycles, and a 35% increase in capacity over the pristine electrode is retained over 50 cycles. In addition, the pristine electrode does not function at a current of 0.64 mA cm–2 and above, while the Co‐doped electrode can retain a capacity of 410 mAh g–1 at a current of 1.28 mA cm–2 (2.4C). Detailed characterization of the electrodes revealed that the improved electrochemical performances are due to the refined microstructure and a higher reaction voltage during the second stage of the lithiation reaction which promotes a deeper lithiation.
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