The effects of γ‐irradiation on the dielectric properties of stretched and poled polyvinylidene fluoride thin films synthesized by solvent cast method are reported. The films are subjected to γ‐irradiation with different doses (25, 50, and 75 kGy). XRD pattern is obtained to identify the presence of α/β phases. Dielectric constant and loss values of the stretched and poled films have been measured, before and after irradiation, and their nature of variation has been studied. β phase is retained even after the irradiation thereby confirming that the radiation damage is not significant. The dielectric loss is minimum in the frequency range 102 to104 Hz, giving the preferable frequency range of operation for devices

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Herein, pristine poly(vinyl alcohol) (PVA) and PVA‐zinc oxide (ZnO) nanocomposite thin films are prepared by solution casting method with different wt% of ZnO (0.1, 0.2, 0.3, 0.5 wt%) nanoparticles with PVA polymer matrix. The addition of ZnO in a PVA matrix induces decrease in the transparency of films. The structural characteristics of prepared thin films are analyzed by X‐ray diffraction (XRD), Fourier transform infrared (FTIR) and Raman spectroscopy. XRD confirms the presence of ZnO structure and β‐phase in the synthesized films. The average crystallite size of the prepared thin films were determined by Scherer's equation. XRD result shows increase in percentage crystallinity of the films. Vibrational modes and functional groups present in pristine PVA and PVA/ZnO thin films are identified by FT‐IR and Raman spectroscopy. FTIR analysis shows the characteristics bands, which corresponds to O–H and Zn–O bands present in the films. Raman spectra of pristine PVA and PVA/ZnO films are reported. Optical characteristics of synthesized pristine PVA and PVA/ZnO nanocomposite thin films are studied by UV–vis spectroscopy. Optical constants like absorption edge, direct bandgap, optical dielectric constant, loss, and optical conductivity were estimated, and optical dispersion parameters are calculated by single oscillator model.