The influence of a basic aqueous solution on a hydrogen-bonding-directed layer-by-layer (LbL) self-assembled film, based on poly(acrylic acid) (PAA) and poly(4-vinylpyridine) (PVP), was investigated. The composition change of a multilayer film in a NaOH solution was monitored by X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and UV-vis spectroscopy. The morphology variation was observed by atomic force microscopy. A two-step variation was observed: the first step is the dissolution of PAA from the film into the basic solution; the second is the gradual reconformation of PVP polymer chains remaining on the substrate, which produces a microporous film. The evidence for the reconformation of the polymer chains was further provided by single molecule force spectroscopy. Both the release of PAA and the formation of the microporous film are attributed to the properties of the LbL film based on hydrogen bonding. This interesting and novel way to fabricate microporous films is envisaged to have potential applications in areas ranging from pharmaceutics to materials science.
The fabrication of stable polyelectrolyte/Au nanoparticle multilayer films was achieved by the UV irradiation of layer‐by‐layer self‐assembled multilayers consisting of diazoresins and Au nanoparticles. The method promises to be a simple and efficient strategy to construct covalently attached organic/inorganic multilayer hybrids.
The stratospheric airship is taken as the research object, and the motion mode analysis of the stratospheric airship is carried out. The influence of key parameters such as the center of mass, the center of buoyance, and the aerodynamic stability moment on the motion mode of stratospheric airship are analyzed and summarized in detail. According to the simulation and analysis results, unlike high-speed and high-dynamic aircrafts such as airplanes, the motion modes of the stratospheric airship are hardly affected by the perturbation of aerodynamic stability moment; the perturbations of the vertical center of mass and the vertical center of buoyancy have a great influence on the pitch pendulum motion modes, and their parameter perturbations affect the frequency of the pitch pendulum motion and also the stability of the pitch pendulum motion; the axial mass center location perturbation not only changes the damping of pitch pendulum motion but also affects the frequency of the yaw motion attitude motion mode to a certain extent.
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