We applied periodic density-functional theory (DFT) to investigate the dehydrogenation of ethanol on a Rh/CeO2 (111) surface. Ethanol is calculated to have the greatest energy of adsorption when the oxygen atom of the molecule is adsorbed onto a Ce atom in the surface, relative to other surface atoms (Rh or O). Before forming a six-membered ring of an oxametallacyclic compound (Rh-CH2CH2O-Ce(a)), two hydrogen atoms from ethanol are first eliminated; the barriers for dissociation of the O-H and the beta-carbon (CH2-H) hydrogens are calculated to be 12.00 and 28.57 kcal/mol, respectively. The dehydrogenated H atom has the greatest adsorption energy (E(ads) = 101.59 kcal/mol) when it is adsorbed onto an oxygen atom of the surface. The dehydrogenation continues with the loss of two hydrogens from the alpha-carbon, forming an intermediate species Rh-CH2CO-Ce(a), for which the successive barriers are 34.26 and 40.84 kcal/mol. Scission of the C-C bond occurs at this stage with a dissociation barrier Ea = 49.54 kcal/mol, to form Rh-CH(2(a)) + 4H(a) + CO(g). At high temperatures, these adsorbates desorb to yield the final products CH(4(g)), H(2(g)), and CO(g).

Extractive speech summarization, with the purpose of automatically selecting a set of representative sentences from a spoken document so as to concisely express the most important theme of the document, has been an active area of research and development. A recent school of thought is to employ the language modeling (LM) approach for important sentence selection, which has proven to be effective for performing speech summarization in an unsupervised fashion. However, one of the major challenges facing the LM approach is how to formulate the sentence models and accurately estimate their parameters for each spoken document to be summarized. This paper presents a continuation of this general line of research and its contribution is two-fold. First, we propose a novel and effective recurrent neural network language modeling (RNNLM) framework for speech summarization, on top of which the deduced sentence models are able to render not only word usage cues but also long-span structural information of word co-occurrence relationships within spoken documents, getting around the need for the strict bag-of-words assumption. Second, the utilities of the method originated from our proposed framework and several widely-used unsupervised methods are analyzed and compared extensively. A series of experiments conducted on a broadcast news summarization task seem to demonstrate the performance merits of our summarization method when compared to several state-of-the-art existing unsupervised methods.

Extractive speech summarization, aiming to automatically select an indicative set of sentences from a spoken document so as to concisely represent the most important aspects of the document, has become an active area for research and experimentation. An emerging stream of work is to employ the language modeling framework along with the Kullback-Leibler divergence measure for extractive speech summarization, which can perform important sentence selection in an unsupervised manner and has shown preliminary success. This paper presents a continuation of such a general line of research and its main contribution is two-fold. First, by virtue of pseudo-relevance feedback, we explore several effective sentence modeling formulations to enhance the sentence models involved in the LM-based summarization framework. Second, the utilities of our summarization methods and several widely-used methods are analyzed and compared extensively, which demonstrates the effectiveness of our methods.

Owing to the rapidly growing multimedia content available on the Internet, extractive spoken document summarization, with the purpose of automatically selecting a set of representative sentences from a spoken document to concisely express the most important theme of the document, has been an active area of research and experimentation. On the other hand, word embedding has emerged as a newly favorite research subject because of its excellent performance in many natural language processing (NLP)-related tasks. However, as far as we are aware, there are relatively few studies investigating its use in extractive text or speech summarization. A common thread of leveraging word embeddings in the summarization process is to represent the document (or sentence) by averaging the word embeddings of the words occurring in the document (or sentence). Then, intuitively, the cosine similarity measure can be employed to determine the relevance degree between a pair of representations. Beyond the continued efforts made to improve the representation of words, this paper focuses on building novel and efficient ranking models based on the general word embedding methods for extractive speech summarization. Experimental results demonstrate the effectiveness of our proposed methods, compared to existing state-of-the-art methods.

Developments of noise robustness techniques are vital to the success of automatic speech recognition (ASR) systems in face of varying sources of environmental interference. Recent studies have shown that exploring low-dimensional structures of speech features can yield good robustness. Along this vein, research on low-rank representation (LRR), which considers the intrinsic structures of speech features lying on some low dimensional subspaces, has gained considerable interest from the ASR community. When speech features are contaminated with various types of environmental noise, its corresponding modulation spectra can be regarded as superpositions of unstructured sparse noise over the inherent linguistic information. As such, we in this paper endeavor to explore the low dimensional structures of modulation spectra, in the hope to obtain more noise-robust speech features. The main contribution is that we propose a novel use of the LRR-based method to discover the subspace structures of modulation spectra, thereby alleviating the negative effects of noise interference. Furthermore, we also extensively compare our approach with several well-practiced feature-based normalization methods. All experiments were conducted and verified on the Aurora-4 database and task. The empirical results show that the proposed LRR-based method can provide significant word error reductions for a typical DNN-HMM hybrid ASR system.