A mixture of lithium thiophenolate, R, -unsaturated ester, and aldehyde in CH 2 Cl 2 afforded Michael/ aldol tandem adducts, -hydroxy-R-(1-phenylthioalkyl) esters, in moderate to good yields with a high syn-aldol selectivity. The reaction proceeded effectively when CH 2 Cl 2 or ether was used as a solvent. The countercation of thiolate proved important; lithium cation provided the best results. The stereoselectivity and yield of the adducts greatly depended on the steric size of the ester group. Lithium selenolate, generated in situ by treatment of diphenyldiselenide with methyllithium, brought similar results, whereas alkoxide was too inert for the reaction. Application of the reaction to methacrylate provided a useful method to form a quaternary carbon center on a similar stereoselective level. In the reaction with crotonates, on the other hand, the anti-Michael selectivity dominated over the syn-aldol selectivity. The tandem adduct was useful for the stereoselective preparation of trisubstituted tetrahydrofuran via radical cyclization, whose configuration was found to be 2,3-trans-3,5-trans.
HESS J1843–033 is a very high energy gamma-ray source whose origin remains unidentified. This work presents, for the first time, the energy spectrum of gamma rays beyond 100 TeV from the HESS J1843–033 region using the data recorded by the Tibet air shower array and its underground muon detector array. A gamma-ray source with an extension of 0.°34 ± 0.°12 is successfully detected above 25 TeV at (α, δ) = (281.°09 ± 0.°10, −3.°76 ± 0.°09) near HESS J1843–033 with a statistical significance of 6.2σ, and the source is named TASG J1844–038. The position of TASG J1844–038 is consistent with those of HESS J1843–033, eHWC J1842–035, and LHAASO J1843–0338. The measured gamma-ray energy spectrum in 25 TeV < E < 130 TeV is described with dN / dE = ( 9.70 ± 1.89 ) × 10 − 16 (E/40 TeV)−3.26±0.30 TeV−1 cm−2 s−1, and the spectral fit to the combined spectra of HESS J1843–033, LHAASO J1843–0338, and TASG J1844–038 implies the existence of a cutoff at 49.5 ± 9.0 TeV. Associations of TASG J1844–038 with SNR G28.6–0.1 and PSR J1844–0346 are also discussed in detail for the first time.
Gamma rays from HESS J1849−000, a middle-aged TeV pulsar wind nebula (PWN), are observed by the Tibet air shower array and the muon detector array. The detection significance of gamma rays reaches 4.0σ and 4.4σ levels above 25 TeV and 100 TeV, respectively, in units of the Gaussian standard deviation σ. The energy spectrum measured between 40 TeV < E < 320 TeV for the first time is described with a simple power-law function of dN / dE = ( 2.86 ± 1.44 ) × 10 − 16 ( E / 40 TeV ) − 2.24 ± 0.41 TeV − 1 cm − 2 s − 1 . The gamma-ray energy spectrum from the sub-TeV (E < 1 TeV) to sub-PeV (100 TeV < E < 1 PeV) ranges, including the results of previous studies, can be modeled with the leptonic scenario, i.e., inverse Compton scattering by high-energy electrons accelerated by the PWN of PSR J1849−0001. On the other hand, the gamma-ray energy spectrum can also be modeled with the hadronic scenario in which gamma rays are generated from the decay of neutral pions produced by collisions between accelerated cosmic-ray protons and the ambient molecular cloud found in the gamma-ray-emitting region. The cutoff energy of cosmic-ray protons E p,cut is estimated as log 10 ( E p , cut / TeV ) = 3.73 − 0.66 + 2.98 , suggesting that protons are accelerated up to the PeV energy range. Our study thus proposes that HESS J1849−000 should be further investigated as a new candidate as a Galactic PeV cosmic-ray accelerator, or “PeVatron.”
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