Enhancement of the conductivity of zinc oxide through doping with hydrogen atoms was examined by using ion implantation of highly resistive thin films deposited by rf magnetron sputtering at room temperature. With a doping of 1×1017 atoms cm−2, the conductivity after annealing at 200 °C in an N2 atmosphere at 1 atm rose from the initial 1×10−7 Ω−1 cm−1 to 5.5×102 Ω−1 cm−1.
Effect of ion implantation on the conductivity of zinc oxide was examined by using highly resistive zinc oxide thin films deposited by rf magnetron sputtering at room temperature to reduce the effect of oxygen vacancies. With the doping by 1×1017 atoms/cm2 gallium the conductivity is 1.0×103/Ω cm for as-implanted film and it increases up to 3.7×103/Ω cm, the highest conductivity reported for zinc oxide films, with raising the annealing temperature in either a nitrogen or oxygen atmosphere. The conductivity of aluminum-doped films is slightly lower than those of gallium-doped films. Among the elements gallium, aluminum, and boron, gallium is the most effective in enhancing the conductivity and boron is the least. The order of the effectiveness is explained by the electronegativity of the dopants.
An oleic acid-coated Fe3O4 nanocrystal self-assembled film was fabricated via drop casting of colloidal particles on a SiO2/Si substrate. The film exhibited bifurcation of the zero-field-cooled and field-cooled magnetizations around 250 K. The nonlinear current-voltage (I-V) characteristics between the source and drain electrodes in both zero and non-zero magnetic fields (H) were observed above and below the bifurcation temperature. A large negative magnetoresistance (MR ≈ -60%) was achieved at 200 K and H = 1 T. Even at 295 K and 0.2 T, the negative MR (∼ -50%) persisted. A Fowler-Nordheim plot and power-law scaling of the I-V characteristics revealed that the current flows through two-dimensional (2D) percolated electron tunneling paths. The enlargement of MR can be attributed to spin-dependent electron tunneling between magnetically coupled Fe3O4 nanocrystals self-assembled in 2D ordered arrays.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.