Magnetostructural coupling in MnMX (M = Co or Ni, X = Si or Ge) system attracts considerable attention for the accompanied multi-magnetoresponsive effects. However, due to the large stress generated from the structural transformation, the alloys become shattered or powder-like, hindering the further investigation and their applications. The possible solution is to embed the MnMX powders into metal matrix. In this paper, we choose Mn0.66Fe0.34Ni0.66Fe0.34Si0.66Ge0.34 as a representative of MnMX alloy and produce Mn0.66Fe0.34Ni0.66Fe0.34Si0.66Ge0.34/Sn composite bulk by hot pressing. The magnetostructural-coupled composites exhibit an improved rate of the transformation temperature shift by magnetic field and broadened operating temperature range. Additionally, we also propose a simple formula based on the entropy-temperature diagram to calculate the isothermal entropy change, which is consistent with the results obtained by the Maxwell relation.

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Twinning has been found to be a dominate mechanism in the γ precipitate strengthened Ni-based superalloys during service at intermediate temperatures. Here, high-resolution transmission electron microscopy and atomistic simulations have been combined to show that the twin nucleation process can be facilitated by Co replacing a fraction of Al in the γ precipitates, due to the negative binding energy of Co-Co atoms. The study further reveals that the presence of Co promotes a new twinning pathway featured with nucleation of one complex stacking fault (CSF) on the middle plane in between two separated CSFs. IMPACT STATEMENT We demonstrate that Co in the γ precipitates promotes a new twinning pathway featured with nucleation of one CSF on the middle plane between two separated CSFs.

Gradient-nanostructured material is an emerging category of material with spatial gradients in microstructural features. The incompatibility between gradient nanostructures (GNS) in the surface layer and coarse-grained (CG) core and their roles in extra strengthening and strain hardening have been well elucidated. Nevertheless, whether similar mechanisms exist within the GNS is not clear yet. Here, interactions between nanostructured layers constituting the GNS in a Ni alloy processed by surface mechanical rolling treatment were investigated by performing unique microtension tests on the whole GNS and three subdivided nanostructured layers at specific depths, respectively. The isolated nanograined layer at the topmost surface shows the highest strength but a brittle nature. With increasing depths, isolated layers exhibit lower strength but enhanced tensile plasticity. The GNS sample’s behavior complied more with the soft isolated layer at the inner side of GNS. Furthermore, an extra strain hardening was found in the GNS sample, leading to a greater uniform elongation (>3%) as compared to all of three constituent nanostructured layers. This extra strain hardening could be ascribed to the effects of the strain gradients arising from the incompatibility associated with the depth-dependent mechanical performance of various nanostructured layers.

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