The drilling recovered high-concentration methane hydrates (maximum 26-48%) in a disseminated form in silty clay sediments in Shenhu area of Pearl River Mouth Basin, South China Sea. Combining the geochemical data, the gas hydrate-bearing sediments are 10 m to 43 m in thickness and located just above the base of the gas hydrate stability zone. The methane content is 96.10-99.91% with small amount of ethane and propane. The baseline chlorinity of pore waters shows 10% lower than that of shallow sediments below and inside the gas hydrate zone. The methane/ethane ratios are higher than 1000 above the gas hydrate zone and less than 1000 at the interval of gas hydrate zone. The depth of sulphate methane interface varies from site to site as 17 to 27 mbsf. These results show that the methane of gas hydrate was mainly originated from microbial activity and the upward methane flux is minor. This is evidenced by the δ 13 C CH4 values of headspace gases from the gravity piston cores and released gases from pressure cores, which range from −74.3‰ PDB to −46.2‰ PDB, with the majority less than −55% PDB. The hydrate deposit is a distributed gas hydrate system in Shenhu area.
[1] Gas hydrate saturations were estimated using five different methods in silt and silty clay foraminiferous sediments from drill hole SH2 in the South China Sea. Gas hydrate saturations derived from observed pore water chloride values in core samples range from 10 to 45% of the pore space at 190-221 m below seafloor (mbsf). Gas hydrate saturations estimated from resistivity (R t ) using wireline logging results are similar and range from 10 to 40.5% in the pore space. Gas hydrate saturations were also estimated by P wave velocity obtained during wireline logging by using a simplified three-phase equation (STPE) and effective medium theory (EMT) models. Gas hydrate saturations obtained from the STPE velocity model (41.0% maximum) are slightly higher than those calculated with the EMT velocity model (38.5% maximum). Methane analysis from a 69 cm long depressurized core from the hydrate-bearing sediment zone indicates that gas hydrate saturation is about 27.08% of the pore space at 197.5 mbsf. Results from the five methods show similar values and nearly identical trends in gas hydrate saturations above the base of the gas hydrate stability zone at depths of 190 to 221 mbsf. Gas hydrate occurs within units of clayey slit and silt containing abundant calcareous nannofossils and foraminifer, which increase the porosities of the fine-grained sediments and provide space for enhanced gas hydrate formation. In addition, gas chimneys, faults, and fractures identified from three-dimensional (3-D) and high-resolution two-dimensional (2-D) seismic data provide pathways for fluids migrating into the gas hydrate stability zone which transport methane for the formation of gas hydrate. Sedimentation and local canyon migration may contribute to higher gas hydrate saturations near the base of the stability zone.
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