This study developed a high-strength molded fiber material (HMFM) using pulp fibers, which could be a good substitute for plastic and solid wood materials. The surface composition, microstructure and thermal properties of HMFM were investigated by XPS, SEM and DSC, respectively. The SEM observations showed that the obvious adhesive substances and agglomeration appeared among fibers, and the inter-fiber contact area and binding tightness increased after the light-delignification. The XPS examination showed that the oxygen-rich composition on the outer surface of HMFM were reduced, and the outer surface coverage of lignin increased from 70.05% to 90.15% after the light-delignification. The DSC observation showed that the thermal stability of HMFM decreased, the temperature for the maximum rate of mass loss decreased from 370 °C to 345.6 °C, and the enthalpy value required for decomposition was reduced from 110.8 J/g to 68.0 J/g after the light-delignification. The mechanical and hydrophobic properties of HMFM were obviously improved after the light-delignification. When the content of lignin decreased from 24.9% to 11.45%, the density of HMFM increased by 6.0%, the tensile strength increased by 22.0%, the bending strength increased by 23.9%, and the water contact angle increased from 64.3°–72.7° to 80.8°–84.3°.
The behavior of pressed poplar chemi-thermomechanical pulping (CTMP) without additive the focus of our study. Four CTMPs with decreasing lignin contents were prepared by the sodium chlorite/acetic acid method and the holocellulose, α-cellulose, pentosan and Klason lignin contents of the delignified CTMPs were determined. The surface composition, aggregation structure and microstructure of the delignified fibers were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM), and the mechanical properties of the fiber material were investigated by means of tensile and bending tests. As shown by XPS, the lignin content of the Pr-CTMP surface layer firstly increased and then decreased as the lignin content of CTMP decreased. With the delignification time increased from 0 to 240 min, the crystallinity index (CrI) of CTMP increased from 60.1% to 65.7%. TheCrIof all CTMPs at different delignification degrees showed significant elevated values after hot-pressing. The fiber cell wall became thinner and the cells were flattened and thus elevated the contact area among fibers and, as a consequence, the density of material gradually increased at higher delignification degrees. The tensile strength increased by ca. 10%, when the lignin content decreased from 24.9% to 13.1%, and by ca. 53%, when the lignin content decreased from 13.1% to nearly zero. The bending strength increased with increasing delignification. When the removal rate of lignin increased from 47% to 54%, the bending strength increased from 101 to 122 MPa.
Using N,N-dimethylacetamide (DMAc) as a reducing agent in the presence of PVP-K30, the stable silver nanoparticles (Ag-NPs) solution was prepared by a convenient method for the in situ reduction of silver nitrate. The cellulose–Ag-NPs composite film (CANF) was cast in the same container using lithium chloride (LiCl) giving the Ag-NPs-PVP/DMAc solution cellulose solubility as well as γ-mercaptopropyltrimethoxysilane (MPTS) to couple Ag-NPs and cellulose. The results showed that the Ag-NPs were uniformly dispersed in solution, and the solution had strong antibacterial activities. It was found that the one-pot synthesis allowed the growth of and cross-linking with cellulose processes of Ag-NPs conducted simultaneously. Approximately 61% of Ag-NPs was successfully loaded in CANF, and Ag-NPs were uniformly dispersed in the surface and internal of the composite film. The composite film exhibited good tensile properties (tensile strength could reach up to 86.4 MPa), transparency (light transmittance exceeds 70%), thermal stability, and remarkable antibacterial activities. The sterilization effect of CANF0.04 against Staphylococcus aureus and Escherichia coli exceed 99.9%. Due to low residual LiCl/DMAc and low diffusion of Ag-NPs, the composite film may have potential for applications in food packaging and bacterial barrier.
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