Li−CO 2 batteries with high theoretical energy densities are recognized as next-generation energy storage devices for addressing the range anxiety and environmental issues encountered in the field of electric transportation. However, cathode catalysts with unsatisfactory activity toward CO 2 absorption and reduction/evolution reactions hinder the development of Li−CO 2 batteries with desired specific capacities and sufficient cycle numbers. In this work, a multifunctional nanofibrous cathode catalyst that integrates N-rich carbon shells embedded with molybdenum carbide nanoparticles and multiwalled carbon nanotube cores was designed and prepared. The N-rich carbon shell could strengthen the absorption capacity of CO 2 and Li 2 CO 3 . The molybdenum carbide nanoparticles would improve the catalytic activity of both CO 2 reduction and evolution reactions. The carbon nanotube cores would provide an efficient network for electron transportation. The synergistic effect of the cathode catalysts enhances the electrochemical performance of Li−CO 2 batteries. A high cycling stability of more than 150 cycles at a current density of 250 mA g −1 with a cutoff capacity of 1000 mAh g −1 and a charge/discharge overpotential of less than 1.5 V is achieved. This work provides a feasible strategy for the design of a high-performance cathode catalyst for lithium−air batteries.
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