The title complex (II~-C~H~)WRU,(CO),(~-NP~)(CZCP~), containing a bridging imido ligand and a p4-V2-acetylide ligand, has been prepared by means of the condensation between ( T ~~-C ~H ~) W ( C O ) ~C = C P ~ and Ru~(CO)&~-NP~), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.
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