In the title complex polymer, [Sr(C10H7N6)2(H2O)2]n, the SrII atom lies on an inversion centre and is coordinated by four N atoms from two bidentate bridging trans-related 5-[4-(1H-imidazol-1-yl)phenyl]tetrazolide ligands [Sr—N = 2.387 (4) Å for the tetrazolide moiety and Sr—N = 2.273 (5) Å for the imidazole moiety], and by two O atoms from water molecules [Sr—O = 2.464 (4) Å], giving a distorted octahedral coordination. Pairs of ligand bridges link the complex units, forming chains which extend along [111] and are inter-associated through Owater—H⋯N hydrogen bonds, giving a two-dimensional network structure parallel to (001). Weak π–π stacking interactions between the benzene and imidazole rings are also present [minimum ring centroid separation = 3.691 (4) Å].
In the title compound, C10H8N6, the tetrazole and benzene rings are close to being coplanar [dihedral angle = 9.90 (16)°], but the imidazole ring is rotated 37.18 (09)° out of the benzene plane. In the crystal, molecules are connected through tetrazole–imidazole N—H⋯N hydrogen bonds, giving rise to zigzag chains, which extend along [010].
In the title complex, [Cd(C8H9N2O4)2(H2O)2]·2C3H7NO, the six-coordinate CdII ion is in a slightly distorted octahedral environment, defined by two O atoms from two coordinated water molecules and two carboxylate O atoms and two N atoms from two N,O-bidentate 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands. In the crystal, complex molecules and dimethylformamide solvent molecules are linked by O—H⋯O and N—H⋯O hydrogen bonds into a two-dimensional supramolecular structure. The propyl groups of the ligands are disordered over two conformations with refined occupancies of 0.680 (7) and 0.320 (7).
In the title compound, [Cd(C10H7N6)2(H2O)2], the CdII atom lies on an inversion centre and is coordinated by four N atoms from 5-[4-(1H-imidazol-1-yl)phenyl]tetrazol-1-ide ligands and two O atoms from the coordinated water molecules in an octahedral arrangement. The complex polymeric chains are interconnected via intermolecular water O—H⋯N hydrogen bonds into a three-dimensional network.
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