Hydrogen-atom (H-atom) transfer at the surface of heterogeneous metal oxides has received significant attention owing to its relevance in energy conversion and storage processes. Here, we present the synthesis and...

Anionic dopants, such as O-atom vacancies, alter the thermochemical and kinetic parameters of proton-coupled electron transfer (PCET) at metal oxide surfaces; understanding the impact is essential for informed material design...

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We report accelerated rates of oxygen-atom transfer from a polyoxovanadate-alkoxide cluster following functionalization with a 4-tertbutylcalix[4]arene ligand. Incorporation of this electron withdrawing ligand modifies the electronics of the metal oxide...