Electrically responsive photonic crystals, capable of
transforming
crystal structures and changing intrinsic structural colors in response
to external electrical energies, can serve as optically active components
for promising technological applications. Unfortunately, the deformation
of inverse opal photonic crystals generally weakens the structural
stability and leads to poor color tuning repeatability, while most
color-tunable colloidal photonic crystals suffer from low color saturation
as a result of small refractive index difference between the colloids
and matrices. Inspired by cephalopod skins, nanometer-sized hollow
silica sphere/poly(3,4-ethylenedioxythiophene)–polystyrene
sulfonate photonic crystals are self-assembled using a scalable coating
technique. The as-engineered photonic crystals exhibit a conspicuous
structural color that is tunable on demand by applying varied voltages.
Importantly, their appearance and expanded crystalline lattice can
be maintained without any electric field under ambient conditions
and simultaneously recovered by applying an oxidation potential. The
reversibility and the dependence of hollow sphere size and thickness
on electrochromic behaviors are also investigated in this study.
The stacked riblet-like shark scales, also known as dermal denticles, allow them to control the boundary layer flow over the skin and to reduce interactions with any biomaterial attached, which guide the design of antifouling coatings. Interestingly, shark scales are with a wide variation in geometry both across species and body locations, thereby displaying diversified antifouling capabilities. Inspired by the multifarious denticles, a stretchable shark scalepatterned silica hollow sphere colloidal crystal/polyperfluoroether acrylatepolyurethane acrylate composite film is engineered through a scalable selfassembly approach. Upon stretching, the patterned photonic crystals feature different short-term antibacterial and long-term anti-biofilm performances with a distinguished color response under varied elongation ratios. To gain a better understanding, the dependence of elongation ratio on antiwetting behaviors, antifouling performances, and structural color changes has also been investigated in this research.
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