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The removal of Pb (II) and Cu (II) ions by using marine red macroalgae (Gracilaria changii) as a biosorbent material was evaluated through the batch equilibrium technique. The effect of solution pH on the removal of metal ions was investigated within the range of 2–7. The response surface methodology (RSM) technique involving central composite design (CCD) was utilised to optimise the three main sorption parameters, namely initial metal ion concentration, contact time, and biosorbent dosage, to achieve maximum ion removal. The models’ adequacy of response was verified by ANOVA. The optimum conditions for removal of Pb (II) and Cu (II) were as follows: pH values of 4.5 and 5, initial concentrations of 40 mg/L, contact times of 115 and 45 min, and biosorbent dosage of 1 g/L, at which the maximum removal percentages were 96.3% and 44.77%, respectively. The results of the adsorption isotherm study showed that the data fitted well with the Langmuir’s model for Pb (II) and Cu (II). The results of the adsorption kinetic study showed that the data fitted well with the pseudo-second order model for Pb (II) and Cu (II). In conclusion, red alga biomass exhibits great potential as an efficient low-cost sorbent for removal of metal ions.

Oily-biological sludge (OBS) generated from petroleum refineries has high toxicity. Therefore, it needs an appropriate disposal method to reduce the negative impacts on the environment. The anaerobic co-digestion process is an effective method that manages and converts organic waste to energy. For effective anaerobic digestion, a co-substrate would be required to provide a suitable environment for anaerobic bacteria. In oily-biological sludge, the carbon/nitrogen (C/N) ratio and volatile solids (VS) content are very low. Therefore, it needs to be digested with organic waste that has a high C/N ratio and high VS content. This study investigates the use of sugarcane bagasse (SB) as an effective co-substrate due to its high C/N ratio and high VS content to improve the anaerobic co-digestion process with oily-biological sludge. The sugarcane bagasse also helps to delay the toxicity effect of the methane bacteria. Batch anaerobic co-digestion of oily-biological sludge was conducted with sugarcane bagasse as a co-substrate in twelve reactors with two-liter capacity, each under mesophilic conditions. The interaction effect of a C/N ratio of 20-30 and a VS co-substrate/VS inoculum ratio of 0.06-0.18 on the methane yield (mL CH4/g VSremoved) was investigated. Before the anaerobic digestion, thermochemical pre-treatment of the inoculum and co-substrate was conducted using sodium hydroxide to balance their acidic nature and provide a suitable pH environment for methane bacteria. Design and optimization for the mixing ratios were carried out by central composite design-response surface methodology (CCD-RSM). The highest predicted methane yield was found to be 63.52 mL CH4/g VSremoved, under optimum conditions (C/N ratio of 30 and co-substrate/inoculum ratio of 0.18).