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Precipitation in the high-altitude Indus basin governs its renewable water resources affecting water, energy and food securities. However, reliable estimates of precipitation climatology and associated hydrological implications are seriously constrained by the quality of observed data. As such, quantitative and spatiotemporal distributions of precipitation estimated by previous studies in the study area are highly contrasting and uncertain. Generally, scarcity and biased distribution of observed data at the higher altitudes and measurement errors in precipitation observations are the primary causes of such uncertainties. In this study, we integrated precipitation data of 307 observatories with the net snow accumulations estimated through mass balance studies at 21 major glacier zones. Precipitation observations are adjusted for measurement errors using the guidelines and standard methods developed under the WMO's international precipitation measurement intercomparisons, while net snow accumulations are adjusted for ablation losses using standard ablation gradients. The results showed more significant increases in precipitation of individual stations located at higher altitudes during winter months, which are consistent with previous studies. Spatial interpolation of unadjusted precipitation observations and net snow accumulations at monthly scale indicated significant improvements in the quantitative and spatio-temporal distribution of precipitation over the unadjusted case and previous studies. Adjustment of river flows revealed only a marginal contribution of net glacier mass balance to river flows. The adjusted precipitation estimates are more consistent with the corresponding adjusted river flows. The study recognized that the higher river flows than the corresponding precipitation estimates by the previous studies are mainly due to underestimated precipitation. The results can be useful for water balance studies and bias correction of gridded precipitation products for the study area.

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Good stability and reproducibility are important factors in determining the place of any material in their respective field and these two factors also enable them to use in various applications. At present, transition metal carbides (TMCs) have high demand either in the two-dimensional (2D) form (MXene) or as nanocomposites, nanoparticles, carbide films, carbide nano-powder, and carbide nanofibers. They have shown good stability at high temperatures in different environments and also have the ability to show adequate reproducibility. Metal carbides have shown a broad spectrum of properties enabling them to engage the modern approach of multifacet material. Several ways have been routed to synthesize metal carbides in their various forms but few of those gain more attention due to their easy approach and better properties. TMCs find applications in various fields, such as catalysts, absorbents, bio-sensors, pesticides, electrogenerated chemiluminescence (ECL), anti-pollution and anti-bacterial agents, and in tumor detection. This article highlights some recent developments in the synthesis methods and applications of TMCs in various fields.

Various concentrations of Mg-doped ZnO nanorods (NRs) were prepared using co-precipitation technique. The objective of this study was to improve the photocatalytic properties of ZnO. The effect of Mg doping on the structure, phase constitution, functional groups presence, optical properties, elemental composition, surface morphology and microstructure of ZnO was evaluated with XRD, FTIR, UV–Vis spectrophotometer, EDS, and HR-TEM, respectively. Optical absorption spectra obtained from the prepared samples showed evidence of blueshift upon doping. XRD results revealed hexagonal wurtzite phase of nanocomposite with a gradual decrease in crystallite size with Mg addition. PL spectroscopy showed trapping efficiency and migration of charge carriers with electron–hole recombination behavior, while HR-TEM estimated interlayer d-spacing. The presence of chemical bonding, vibration modes and functional groups at the interface of ZnO was revealed by FTIR and Raman spectra. In this study, photocatalytic, sonocatalytic and sonophotocatalytic performance of prepared NRs was systematically investigated by degrading a mixture of methylene blue and ciprofloxacin (MBCF). Experimental results suggested that improved degradation performance was shown by Mg-doped ZnO NRs. We believe that the product synthesized in this study will prove to be a beneficial and promising photocatalyst for wastewater treatment. Conclusively, Mg-doped ZnO exhibited substantial (p < 0.05) efficacy against gram-negative (G-ve) as compared to gram-positive (G+ve) bacteria. In silico molecular docking studies of Mg-doped ZnO NRs against DHFR (binding score: − 7.518 kcal/mol), DHPS (binding score: − 6.973 kcal/mol) and FabH (− 6.548 kcal/mol) of E. coli predicted inhibition of given enzymes as possible mechanism behind their bactericidal activity.