ABSTRACT:A study was conducted to investigate the trace metal pollution of water and sediments of downstream of Tsurumi River, Yokohama, Japan. Twenty samples of water and sediments were collected from the river starting from Tokyo bay side up to the junction point of the Yagami River. Results show that the mean concentrations of chromium, cupper and nickel in water greatly exceed (>100 times) the surface water standard. The concentration of molybdenum and lead was also higher than standard values while iron and manganese was lower than that of surface water standard. The mean concentration of zinc, cupper, cadmium, lead, chromium, vanadium, bromine and iodine was 381.1, 133.0, 1.0, 40.8, 102.9, 162.0, 71.5 and 10.6 µg/g sediments, respectively and was greatly exceed the average worldwide shale concentrations and average Japanese river sediment values. However, mean concentration of arsenic, nickel and strontium was 11.0, 36.6 and 164.6 µg/g sediments, respectively which was lower than the average shale value. Other analyzed trace metals, including barium, zirconium, rubidium, yttrium, tin, antimony, cesium, lanthanum, cerium, praseodymium and neodymium were detected in river sediments; the concentration of which was close to the Japan's river sediment average values. Pollution load index values of the sites of the studied area ranged from 1.24 to 7.65 which testify that the river sediments are polluted. The PLI value of the area was, however, high (6.53) as the concentration of trace metals like zinc, cupper, cadmium, lead and chromium were very high and were the major pollutants.

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Background Sepsis is a major contributor to neonatal mortality, particularly in low-income and middle-income countries (LMICs). WHO advocates ampicillin-gentamicin as first-line therapy for the management of neonatal sepsis. In the BARNARDS observational cohort study of neonatal sepsis and antimicrobial resistance in LMICs, common sepsis pathogens were characterised via whole genome sequencing (WGS) and antimicrobial resistance profiles. In this substudy of BARNARDS, we aimed to assess the use and efficacy of empirical antibiotic therapies commonly used in LMICs for neonatal sepsis.Methods In BARNARDS, consenting mother-neonates aged 0-60 days dyads were enrolled on delivery or neonatal presentation with suspected sepsis at 12 BARNARDS clinical sites in

A study was undertaken to determine the contents of trace metals in 60 topsoils and 80 brinjal fruits samples from a famous brinjal-producing area of Bangladesh using atomic absorption spectrophotometer. The study also looked at soil pollution levels, dietary intake of nutritionally important trace elements, and human health risks from toxic metals induced by dermal soil exposure and consumption of brinjal. The content of Pb, Ni, Cd, Cu, Fe, Mn, and Zn in brinjal fruits harvested from farmer′s fields ranged from 0.204–0.729, 0.031–0.212, < 0.010–0.061, 1.819–2.668, 3.267–5.910, < 0.010–0.866 and 2.160–3.846 µg g-1, respectively, while the amount of Cr was negligible. The calculated enrichment factors showed that 70, 50, and 25% of soil sampling sites had values in the 2.00–5.00 range for Pb, Zn, and Cd, respectively, while 30% of sites had values > 5.00 for Cd, indicating moderate to significant enrichment of these metals in the soil. The study also revealed that brinjal consumption provides a tiny amount of nutritionally important trace elements required for an adult human. Regarding the computed incremental lifetime cancer risks (ILCR), the study revealed that the values for Pb and Ni in all samples and Cd in 40% of samples were several hundred times higher for males and females than the USEPA threshold level due to oral ingestion of brinjal fruits. In contrast, dermal exposures to soil trace elements were within an acceptable range. The PCA results revealed that the contents of Cd, Pb, Ni, and Cu in soils showed strong positive correlations with those elements present in brinjal. The current study suggests future traceability research, focusing on pinpointing potential entry routes for toxic elements into the vegetable food chain.

The study was conducted to determine heavy metal contents in industrial wastewater and contaminated soils of Bhaluka, Mymensingh and to assess their pollution level. A total of 9 industrial wastewater and 12 contaminated farm soil samples were collected directly from the farmers’ fields of Bhaluka area and analysed for this study. Considering EC, salinity and TDS, 56 to 89% wastewater samples were found problematic for long term irrigation. The concentration of CO3, HCO3 and Cl in wastewater ranged from 0.20-1.60, 2.0-11.2 and 1.30-4.79 me L-1, respectively and the content of Ca, Mg, Na and K in wastewater ranged from 16.03-52.10, 4.86-21.87, 101.98-678.90 and 5.59-48.63 mg L-1, respectively. The study results revealed that all wastewater samples were found unsuitable for irrigation in respect of CO3, HCO3 and K. Among the heavy metals studied, Pb, Cd and Fe concentrations in all wastewater samples and Mn content in 5 samples were found above than the acceptable limit for irrigation. The concentration of Zn, Cr, Cu, Pb, Ni, Cd, Mn and Fe in wastewater irrigated soils of Bhaluka industrial area ranged from 50.48 to 448.56, 47.22 to 83.65, 19.13 to 328.23, 42.37 to 77.96, 22.93 to 43.86, 0.70 to 1.40, 161.5 to 341.7 and 38105 to 65399 μg g-1, respectively. Considering geoaccumulation index, the Igeo values for Pb and Cd for all locations of the study area exhibited positive values (0.495< Igeo <1.624), that means Igeo class: 1-2, indicate moderately polluted soil quality. On the other hand, as regards to enrichment factor (EFc), 9 locations for Pb, 5 for Cd, 1 for Zn and 1 for Cu had EFc values > 5.0, indicate contaminated soil quality. The study concluded that industrial wastewater used for irrigation was directly linked with the heavy metals deposition in the farm soils.

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The study was undertaken to evaluate groundwater quality both for drinking and irrigation usage collected from the Sadar upazila of Jamalpur district, Bangladesh. Total 20 groundwater samples were collected from the whole area and analysed for various physicochemical parameters following standard protocols at the Department of Agricultural Chemistry, Bangladesh Agricultural University, Mymensingh during March to December 2017. Concentrations of different heavy metal (Fe, Mn, Cu, Pb, Cr, Cd and Zn) in groundwater samples were measured by an atomic absorption spectrophotometer (AAS). Major cation chemistry showed their dominance in order of Ca > Mg > Na > K. Among the anions, HCO3 was the most dominating ion, which makes all groundwater unsuitable for irrigation. But considering major cations and anions, all groundwater samples were rated as suitable for drinking. In context of heavy metals, the amounts of Mn, Cd and Pb in groundwater were comparatively higher than the standard limits, which makes 14, 8 and 19 samples problematic for irrigation, and 13, 18 and 1 samples unsuitable for drinking, respectively. Electrical conductivity (EC) and sodium adsorption ratio (SAR) reflected that all groundwater samples were low to medium salinity (C1-C2) and low alkalinity (S1) hazards classes. As regards to hardness, out of 20 groundwater samples, 9 samples were classified as moderately hard, 10 were hard and only 1 sample was very hard in quality. According to residual sodium carbonate (RSC), 18 groundwater samples were found in suitable class, 1 sample was rated as marginal and the rest 1 was categorised as unsuitable class. The study concluded that HCO3, Mn, Cd and Pb were the major contaminants in groundwater of Sadar upazila of Jamalpur district, Bangladesh. Finally, the study suggested that the groundwater in this area needs to treat to minimise the amount of contaminants before using both for irrigation and drinking.