Dielectric
polymer nanocomposites
with a high breakdown field and high dielectric constant have drawn
significant attention in modern electrical and electronic industries
due to their potential applications in dielectric and energy storage
systems. The interfaces of the nanomaterials play a significant role
in improving the dielectric performance of polymer nanocomposites.
In this work, polydopamine (dopa)-functionalized TiO2–BaTiO3–TiO2 (TiO2–BT–TiO2@dopa) core@double-shell nanoparticles have been developed
as novel nanofillers for high-energy-density capacitor applications.
The hierarchically designed nanofillers help in tailoring the interfaces
surrounding the polymer matrix as well as act as individual capacitors
in which the core and outer TiO2 shell function as a capacitor
plate because of their high electrical conductivity while the middle
BT layer functions as a dielectric medium due to high dielectric constant.
Detailed electrical characterizations have revealed that TiO2–BT–TiO2@dopa/poly(vinylidene fluoride)
(PVDF) possesses a higher relative dielectric permittivity (εr), breakdown
strength (E
b), and energy density as compared
to those of PVDF, TiO2/PVDF, TiO2@dopa/PVDF,
and TiO2–BT@dopa/PVDF polymer nanocomposites. The
εr and energy density of TiO2–BT–TiO2@dopa/PVDF were 12.6 at 1 kHz and 4.4 J cm–3 at 3128 kV cm–1, respectively, which were comparatively
much higher than those of commercially available biaxially oriented
polypropylene having εr of 2.2 and the energy density
of 1.2 J cm–3 at a much higher electric field of
6400 kV cm–1. It is expected that these results
will further open new avenues for the design of novel architecture
for high-performance polymer nanocomposite-based capacitors having
core@multishell nanofillers with tailored interfaces.
In this work, we have studied the role of a linker across the interface in a multi-layered polymer nanocomposite-based capacitor using barium titanate (BT) nanofibers (NFs) as nanofillers and polyvinylidene fluoride (PVDF) as the polymer matrix.
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