This work addressed one step preparation method to form a novel nano material composite of graphene oxide nanosheet (GO) functionalized with low-cost tri-sodium citrate (C), using, teteraethylorthosilicate (TEOS) as a cross-linker. The prepared composite (GO–C) was characterized using various advanced techniques. Among these techniques, the TGA provided interesting information concerning the functionalization process. Within this process, the (–OH) groups that located at the GO-surface were consumed in the modification process which leads to increase the thermal stability of the resulted composite. Cationic organic methylene blue (MB) and crystal violet (CV), and inorganic copper (Cu2+) and cobalt (Co2+) pollutants were displayed as a model to assess their removal performance by the developed composite (GO–C) from aqueous solution, through batch technique. According to Langmuir isotherm the GO–C present an excellent adsorption capacity for MB (222.22 mg g−1), CV (270.27 mg g−1), Cu2+ (163.4 mg g−1) and Co2+ (145.35 mg g−1) which were more than the adsorption capacities found in literature. Additionally, the regenerated composite presents higher removal ability than the original composite.
Lanthanides are widely used in several advanced technologies, and the presence of heavy metal ions as traces reduce their efficiencies. Hence, adsorption of some heavy metals from Lanthanides aqueous solution using previously prepared graphene oxide-citrate (GO-C) composite was reported. In this regard, the GO-C was applied to remove various heavy metal ions (Fe, Ni, Mn) through the batch technique. The GO-C after the adsorption process was characterized by various advanced techniques. The results obtained from the experimental investigations revealed that the GO-C showed a rapid equilibrium adsorption time (1.0 min) for all the studied heavy metal ions. Moreover, the adsorption isotherm data for Fe3+, Mn2+, and Ni2+ was fit by the Langmuir isotherm model with excellent adsorption capacity for Fe3+ (535.0 mg/g), Mn2+ (223.22 mg/g), and Ni2+ (174.65 mg/g). Furthermore, the GO-C can be reused over five times to enhance the removal efficiency. Interestingly, the GO-C adsorbent achieved removal performance reached 95.0% for the Fe3+ and ≥ 35.0% for Ni, Mn, Co, and Cu compared to < 1% for lanthanides metal ions.
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