Scientists proved that municipal sewage sludge contains many dangerous pathogens, toxic heavy metals, endocrine disruptors, drains, storm water runoff, hospitals, and industrial plants. Sewage sludge represents an extremely high ecological hazard to the environment. Due to the increasing amount of sludge generated from the wastewater treatments plants a strong demand for environmentally and effective safe reuse has arisen. One potential use of that waste is its incorporation in the production of ceramic tiles. The main aim of present work was to study the possibility of usage of this hazardous waste in floor ceramic tiles industry. A dried sludge waste was added in percentages from 5% up to 35% to a standard floor tile mix, molded, pressed uniaxially at 30 MPa and then fired at temperatures reaching 1150°C for 15 min soaking time. The properties of both green and fired tiles were investigated as function of percent waste added. The vitrification parameters, which are linear firing shrinkage, water absorption, apparent porosity, and mechanical property, were determined and compared with ISO standards. Fired samples of the proposed mixtures were investigated by scanning electron microscope (SEM). It was possible to obtain tiles that abided by ISO standards for maximum addition of 7% sludge fired at 1150°C (for water absorption < 10%), and 10% sludge or 5% sludge for tiles fired at 1150°C and 1100°C, respectively (for water absorption > 10%), which are recommended for both their economic and environmental benefits.
Background: The marble and granite industries in Egypt produce a vast amount of by-product slurry waste that could be used in green mortar production suitable for construction purposes. This research highlights the effect of the chemical constituents of marble and granite waste powders on the compressive strength of the green concrete produced. A chemical analysis of the constituents of granite and marble wastes was compared with those of the cement to study the effect of these components on the hydration reaction inside the mixture. The experiment was based on replacing the same proportions of sand and cement in the green concrete mixes with each of granite and marble waste powders after dissolving it in the water content. Results: The study revealed that by replacing 5% of cement in (NC5) mix, 10% of sand in (NF10) mix, as well as 5% of cement and 10% of sand in (NC5 + NF10) mix, by granite waste powder, the compressive strength values increased by 33%, 39%, and 41%, respectively. This was due to the presence of more than 26% fine free silica particles in granite which undergo pozzolanic reaction with calcium hydroxide present in mortar pores producing calcium silicate hydrate (CSH) crystals resulting in high strength to the cement mortar. For the same mixes containing marble powder, the compressive strength showed less values by − 14%, 10%, and 0% for NC5, NF10, and NC5 + NF10 mixes, respectively, when compared to the control mix values. Conclusion: Although the waste particles worked as filler, it was observed that its presence in the mixture improved the particle packing and increased the cohesion of the composites.
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