We present a highly conformable, stretchable, and transparent electrode for application in epidermal electronics based on polydimethylsiloxane (PDMS) and Ag nanowire (AgNW) networks. With the addition of a small amount of a commercially available nonionic surfactant, Triton X, PDMS became highly adhesive and mechanically compliant, key factors for the development of conformable and stretchable substrates. The polar functional groups present in Triton X interacted with the Pt catalyst present in the PDMS curing agent, thereby hindering the cross-linking reaction of PDMS and modulating the mechanical properties of the polymer. Due to the strong interactions that occur between the polar functional groups of Triton X and AgNWs, AgNWs were effectively embedded in the adhesive PDMS (a-PDMS) matrix, and the highly enhanced conformability, mechanical stretchability, and transparency of the a-PDMS matrix were maintained in the resulting AgNW-embedded a-PDMS matrix. Finally, wearable strain and electrocardiogram (ECG) sensors were fabricated from the AgNW-embedded a-PDMS. The a-PDMS-based strain and ECG sensors exhibited significantly improved sensing performances compared with those of the bare PDMS-based sensors because of the better stretchability and conformability to the skin of the former sensors.
In this study, a transparent and stretchable thin-film capacitive strain sensor based on patterned Ag nanowire networks (AgNWs) was successfully fabricated. The AgNWs were patterned using a capillary force lithography (CFL) method and were embedded onto the surface of the polydimethylsiloxane substrate. The strain (ε) sensitivity of the capacitive strain sensor was controlled and enhanced by patterning the AgNWs into electrodes with an interdigitated shape. The interdigitated capacitive strain sensor (ICSS) is expected to have -1.57 gauge factor (GF) at 30% ε by calculation, which is much higher than the sensitivity of typical parallel-plate-type capacitive strain sensors. Because of the interdigitated pattern of the electrodes, the GF of the ICSS was increased up to -2.0. The ICSS had no hysteresis behavior up to ε values of 15% and showed stable ε sensing performance during the repeated stretching test at ε values of 10% for 1000 cycles. Furthermore, there was no cross talk between ε and pressure sensing in the AgNW-based ICSS, which was found to be insensitive to externally applied pressure. The ICSS was then used to detect the finger and wrist muscle motions of the human body to simulate its application to large and small ε sensing.
Self-powered
sensors have attracted significant interest for individual
wearable device operation. Here, transparent and wearable single-electrode
triboelectric nanogenerators (SETENGs) with high power generation
are created using electrospun Ag nanowires (AgNWs)/poly(vinylidenefluoride-cotrifluoroethylene)
[P(VDF-TrFE)] composite nanofibers (NFs). The SETENGs generate an
output power density of up to 217 W/m2 with repetitive
contact and separation from the surface of a latex glove. In electrospun
P(VDF-TrFE) NFs, the crystalline β-phase is highly oriented
by oxygen-containing functional groups on the surface of AgNWs, endowing
the F-rich surface with high electron negativity and enabling efficient
triboelectrification. Additionally, 80% transmittance at a light wavelength
of 550 nm, mechanical stability, and durability after 10 000
cycles at 10% strain are confirmed by filling the NF pores with plasma
desorption mass spectrometry. Our SETENG acts as an effective energy
harvester by powering 45 light-emitting diodes and as an excellent
real-time, self-powered touch panel.
We present patterned Ag-nanowire (AgNW) networks for their application to transparent electrodes in flexible devices. Using capillary-force-based soft lithography (CFL), we formed 25- to 30-µm-wide line patterns of AgNWs on flexible polymer substrates. Organic light-emitting diodes (OLEDs) and transparent thin-film heaters (TFHs) were successfully fabricated on the patterned substrates, which verified the potential of AgNW patterns formed by CFL as interconnects in flexible devices.
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