In
the development of low-cost, efficient, and environmentally
friendly thin-film solar cells (TFSCs), the search continues for a
suitable inorganic colloidal nanocrystal (NC) ink that can be easily
used in scalable coating/printing processes. In this work, we first
report on the colloidal synthesis of pure wurtzite (WZ) Cu2SnS3 (CTS) NCs using a polyol-mediated hot injection route,
which is a nontoxic synthesis method. The synthesized material exhibits
a random distribution of CTS nanoflakes with an average lateral dimension
of ∼94 ± 15 nm. We also demonstrate that CTS NC ink can
be used to fabricate low-cost and environmentally friendly TFSCs through
an ethanol-based ink process. The annealing of as-deposited CTS films
was performed under different S vapor pressures in a graphite box
(volume; 12.3 cm3), at 580 °C for 10 min using a rapid
thermal annealing (RTA) process. A comparative study on the performances
of the solar cells with CTS absorber layers annealed under different
S vapor pressures was conducted. The device derived from the CTS absorber
annealed at 350 Torr of S vapor pressure showed the best conversion
efficiency 2.77%, which is the first notable efficiency for an CTS
NCs ink-based TFSC. In addition, CTS TFSC’s performance degraded
only slightly after 50 days in air atmosphere and under damp heating
at 90 °C for 50 h, indicating their good stability. These results
confirm that WZ CTS NCs may be very attractive and interesting light-absorbing
materials for fabricating efficient solar-harvesting devices.
A common feature of the inorganic thin films including Cu(In,Ga)(S,Se)2 fabricated by nonvacuum solution-based approaches is the doubled-layered structure, with a top dense inorganic film and a bottom carbon-containing residual layer. Although the latter has been considered to be the main efficiency limiting factor, (as a source of high series resistance), the exact influence of this layer is still not clear, and contradictory views are present. In this study, using a CISe as a model system, we report experimental evidence indicating that the carbon residual layer itself is electrically benign to the device performance. Conversely, carbon was found to play a significant role in determining the depth elemental distribution of final film, in which carbon selectively hinders the diffusion of Cu during selenization, resulting in significantly Cu-deficient top CISe layer while improving the film morphology. This carbon-affected compositional and morphological impact on the top CISe films is a determining factor for the device efficiency, which was supported by the finding that CISe solar cells processed from the precursor film containing intermediate amount of carbon demonstrated high efficiencies of up to 9.15% whereas the performances of the devices prepared from the precursor films with very high and very low carbon were notably poor.
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