A high-quality perovskite film is a key aspect contributing to high photovoltaic performance of all-inorganic perovskite solar cells. We herein demonstrate that the addition of methylammonium iodide (MAI) influences effectively both the tailored film morphology and precise crystal growth to construct high-quality CsPbI2Br films. It is found that an MAI additive retards the crystallization kinetics to control the inorganic perovskite films to form a highly crystalline α-CsPbI2Br structure consisting of microsized grains with reduced defect density. The optimal MAI additive (10 wt %) achieves a power conversion efficiency (PCE) of 10.40% for the CsPbI2Br-based all-inorganic perovskite solar cells, which is >30% enhancement from 6.95% of the pristine one. The solar cells employing the MAI additive possess high operational and thermal stability, retaining >70% of the original PCE after aging for 1500 h in ambient atmosphere and under continuous heating at 85 °C for 30 h, respectively. The photovoltaic performance with an indoor light source was also examined using a white light-emitting diode (6500 K, 1000 lux), showing promising PCEs of 23.51% with a stabilized power output of 21.15%.
: A highly porous nonwoven thermoplastic polyurethane (TPU)/Polypropylene (PP) triboelectric nanogenerator (N-TENG) was developed. To fabricate the triboelectric layers, the TPU nanofiber was directly electrospun onto the nonwoven PP at different basis weights (15, 30, and 50 g/m2). The surface morphologies and porosities of the nonwoven PP and TPU nanofiber mats were characterized by field-emission scanning electron microscopy and porosimetry. The triboelectric performance of the nonwoven TPU/PP based TENG was found to improve with an increase in the basis weight of nonwoven PP. The maximum output voltage and current of the TPU/PP N-TENG with 50% PP basis weight reached 110.18 ± 6.06 V and 7.28 ± 0.67 µA, respectively, due to high air volume of nonwoven without spacers. In order to demonstrate its practical application as a generator, a TPU/PP N-TENG-attached insole for footwear was fabricated. The N-TENG was used as a power source to turn on 57 light-emitting diodes through human-walking, without any charging system. Thus, owing to its excellent energy-conversion performance, simple fabrication process, and low cost, the breathable and wearable nonwoven fiber-based TENG is suitable for large-scale production, to be used in wearable devices.
Smart textiles have wide applications in various sensing systems since they have the advantage of maintaining the inherent properties of textile such as light weight, flexibility, comfort, and breathability. Therefore, textile-based pressure sensors, one of the smart textiles, have attracted considerable interest in wearable electronics and homecare systems. In this study, to construct a textile-based pressure sensor, a poly(3,4-ethylenedioxythiophene) (PEDOT) thin film was fabricated on a polyethylene terephthalate microfiber fabric by vapor phase polymerization with various concentrations of the oxidant, FeCl 3 . The PEDOT conductive textile showed a change in conductivity depending on the applied pressure. We confirmed the excellent washing and physical durability of the sensor from the stable electrical properties of the PEDOT conductive textile after washing and repeated folding tests. Furthermore, a fully textile-based pressure sensor was successfully fabricated using the highly durable PEDOT, which could simultaneously measure both static and dynamic pressures even during physical deformation, thus suggesting great potential in smart textiles, especially textile-based homecare systems.
For the immediate detection of gaseous strong acids, it is advantageous to employ colorimetric textile sensors based on halochromic dyes. Thus, a rhodamine dye with superior pH sensitivity and high thermal stability was synthesized and incorporated in nylon 6 and polyester fabrics to fabricate textile sensors through dyeing and printing methods. The spectral properties and solubility of the dye were examined; sensitivity to acidic gas as well as durability and reversibility of the fabricated textile sensors were investigated. Both dyed and printed sensors exhibited a high reaction rate and distinctive color change under the acidic condition owing to the high pH sensitivity of the dye. In addition, both sensors have outstanding durability and reversibility after washing and drying.
The combination of the triboelectric effect and static electricity as a triboelectric nanogenerator (TENG) has been extensively studied. TENGs using nanofibers have advantages such as high surface roughness, porous structure, and ease of production by electrospinning; however, their shortcomings include high-cost, limited yield, and poor mechanical properties. Microfibers are produced on mass scale at low cost; they are solvent-free, their thickness can be easily controlled, and they have relatively better mechanical properties than nanofiber webs. Herein, a nano-and micro-fiber-based TENG (NMF-TENG) was fabricated using a nylon 6 nanofiber mat and melt blown nonwoven polypropylene (PP) as triboelectric layers. Hence, the advantages of nanofibers and microfibers are maintained and mutually complemented. The NMF-TENG was manufactured by electrospinning nylon 6 on the nonwoven PP, and then attaching Ni coated fabric electrodes on the top and bottom of the triboelectric layers. The morphology, porosity, pore size distribution, and fiber diameters of the triboelectric layers were investigated. The triboelectric output performances were confirmed by controlling the pressure area and basis weight of the nonwoven PP. This study proposes a low-cost fabrication process of NMF-TENGs with high air-permeability, durability, and productivity, which makes them applicable to a variety of wearable electronics.
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