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Relaxor ferroelectric single crystals have triggered revolution in electromechanical systems due to their superior piezoelectric properties. Here the results are reported on experimental studies of energy harvested from (1-y-x)Pb(In1/2Nb1/2)O3–(y)Pb(Mg1/3Nb2/3)O3–(x)PbTiO3 (PIN-PMN-PT) crystals under high strain rate loading. Precise control of ferroelectric properties through composition, size and crystallographic orientation of domains made it possible to identify single crystals that release up to three times more electric charge density than that produced by PbZr0.52Ti0.48O3 (PZT 52/48) and PbZr0.95Ti0.05O3 (PZT 95/5) ferroelectric ceramics under identical loading conditions. The obtained results indicate that PIN-PMN-PT crystals became completely depolarized under 3.9 GPa compression. It was found that the energy density generated in the crystals during depolarization in the high voltage mode is four times higher than that for PZT 52/48 and 95/5. The obtained results promise new single crystal applications in ultrahigh-power transducers that are capable of producing hundreds kilovolt pulses and gigawatt-peak power microwave radiation.

A new type of energy storage devices utilizing multilayer Pb(Zr0.95Ti0.05)0.98Nb0.02O3 films is studied experimentally and numerically. To release the stored energy, the multilayer ferroelectric structures are subjected to adiabatic compression perpendicular to the polarization direction. Obtained results indicate that electrical interference between layers (10–120 layers) during stress wave transit through the structures has an effect on the generated current waveforms, but no impact on the released electric charge. The multilayer films undergo a pressure‐induced phase transition to antiferroelectric phase at 1.7 GPa adiabatic compression and become completely depolarized, releasing surface screening charge with density equal to their remnant polarization. An energy density of 3 J cm−3 is successfully achieved with giant power density on the order of 2 MW cm−3, which is four orders of magnitude higher than that of any other type of energy storage device. The outputs of multilayer structures can be precisely controlled by the parameters of the ferroelectric layer and the number of layers. Multilayer film modules with a volume of 0.7 cm3 are capable of producing 2.4 kA current, not achievable in electrochemical capacitors or batteries, which will greatly enhance the miniaturization and integration requirements for emerging high‐power applications.

Stress-induced and thermal-induced depolarization studies along with X-ray diffraction were performed on lead zirconate titanate ferroelectrics of different compositions, PbZr0.52Ti0.48O3 (PZT 52/48) and PbZr0.95Ti0.05O3 (PZT 95/5). Specimens were shock loaded perpendicular to the polarization vector. It was found that the polarity of the stress-induced charge released by PZT 52/48 and 95/5 was opposite to the polarity of the charge generated due to the piezoelectric effect. PZT 52/48 was only partially (45%) depolarized under 1.5 ± 0.1 GPa mechanical compression, as opposed to PZT 95/5 which was fully depolarized. The experimental results indicate that the stress-induced depolarization mechanisms are different for these two compositions. PZT 52/48 is transformed to a state with lower polarization, while PZT 95/5 undergoes a phase transition to a non-polar antiferroelectric phase.

No abstract

Experimental and digital simulation studies of the generation of seed currents by an ultracompact (8.66–8.75 cm3 in volume) ferromagnetic explosive-driven generator of primary power (FMG) loaded on the coaxial single-turn seeding coil of a magnetocumulative generator (MCG) have been performed. The operation of the FMG is based on transverse shock wave demagnetization of Nd2Fe14B high-energy hard ferromagnets. The FMG is capable of producing in the coaxial seeding coil of MCG a seed current with peak amplitude I(t)max=3.0 kA and full width at half maximum of 60 μs. The methodology was developed for digital simulation of the seeding processes in the combined FMG/MCG system.

Complete stress-induced depolarization of relaxor ferroelectric crystals Complete stress-induced depolarization of relaxor ferroelectric crystals without Complete stress-induced depolarization of relaxor ferroelectric crystals without transition through a non-polar phase transition through a non-polar phase

The action of transverse shock waves (the shock wave propagates across the magnetization vector M) on the magnetic phase state of a Nd2Fe14B high-energy hard ferromagnetic was investigated experimentally. The design of the ferromagnetic sample, which was made as a hollow cylinder, has made it possible to dramatically reduce the amount of the explosive that initiates a transverse shock wave in Nd2Fe14B to 1.0 g (for Nd2Fe14B samples weighing 67.5 g). The results of the experiment have shown that the transverse shock wave propagating through Nd2Fe14B causes “hard ferromagnetic-to-paramagnetic” phase transformation terminating by practically complete demagnetization of Nd2Fe14B. Pulse generators based on the transverse shock wave demagnetization of hollow cylindrical Nd2Fe14B samples with diameter of 25.4 mm and length of 19.1 mm are capable of producing high-voltage pulses [peak voltage of 11.3 kV, full width at half maximum (FWHM) of 4.5 μs] and high-current pulses (peak current of 1.93 kA, FWHM of 100 μs, peak power of 27.0 kW). The effect of transverse shock wave demagnetization of high-energy hard ferromagnetic, Nd2Fe14B, was detected.