Azopolymers are known to exhibit a strong light responsivity known as athermal photofluidization. Although the underlying physics is still under debate, athermal photofluidization has been demonstrated to trigger mass-migration according to the polarization of a proper illumination light. Here, a polymer blend is proposed wherein a commercial azo-polyelectrolyte is mixed with a passive polymer. The blend is patterned as an array of micro-pillars that are individually exposed to visible laser illumination. Thanks to the interplay between the two blend components, a reversible and controlled deformation of the micro-pillars by periodically tuning the laser polarization in time is demonstrated. A reduced mobility of the azo-compound allows to repeatibly elongate and rotate micro-pillars along specific directions, with no significant material flow outisde the initial volume and no significant degradation of the structure morphology over several cycles. The proposed work suggests new degrees of freedom in controlling the mechanical features of micro-patterned light-responsive materials that can be usefully exploited in many application fields.

A one-dimensional photonic crystal (1DPC) based on a planar stack of dielectric layers is used as an optical transducer for biosensing, upon the coupling of TE-polarized Bloch Surface Waves (BSW). The structure is tailored with a polymeric layer providing a chemical functionality facilitating the covalent binding of orienting proteins needed for a subsequent grafting of antibodies in an immunoassay detection scheme. The polymeric layer is impregnated with Cy3 dye, in such a way that the photonic structure can exhibit an emissive behavior. The BSW-coupled fluorescence shift is used as a means for detecting refractive index variations occurring at the 1DPC surface, according to a label-free concept. The proposed working principle is successfully demonstrated in real-time tracking of protein G covalent binding on the 1DPC surface within a fluidic cell.

The light-induced deformation of a micro-textured photo-sensitive polymeric material is exploited for modifying the surface hydrophobicity along deterministic directions. Arrays of azopolymeric micro-pillars are fabricated over large area and irradiated with a green laser. Upon laser irradiation, the micro-pillars deform reversibly along a direction parallel to the laser polarization, resulting in elongated shapes with controllable eccentricity. Such a locally anisotropic topography induces a directional yet reversible change of hydrophobicity, as measured by contact angles varying within a range of 30°.

The surface of PDMS composites containing copper spiky particles was treated using atmospheric pressure plasma to optimize surface tension for PEDOT:PSS inkjet printed electrodes. Quantitative comparison based on image analysis was done.

We report a metal-dielectric planar structure which provides high efficiency coupling of fluorescence at distances over 100 nm away from the metal surface. This hybrid metal-dielectric waveguide (MDW) consists of a continuous metal film coated with a dielectric layer. We observed efficient long-range coupling of Rhodamine B on top of a 130 nm layer of silica resulting in a narrow angular distribution of the emission. The high efficiency radiation through the Ag film appears to be due to coupling of the fluorophore to an optical waveguide mode with a long propagation length and a narrow resonance. The results were consistent with simulations. These multi-layer structures can be made using vapor deposition and/or spin coating and the silica surface can be used for conjugation to biomolecules and surface-selective detection. This simple hybrid metal-dielectric structures provides new opportunities for fluorescence sensing, genomics, proteomics and diagnostics.