thermomechanical processing routes which introduce high densities of dislocations and interfaces into materials. These defect populations introduce long-range stress fields, enabling substantial strengthening of materials. Thus, processing with the aim to introduce high densities of lattice defects into materials is a wellestablished and efficient method to enhance their strength. [12] Yet, when single-phase metallic materials have few defects such as in the recrystallized state and at the beginning of plastic yielding, they often have insufficient intrinsic lattice friction and thus low flow stress. [13,14] The lattice friction, quantified by the Peierls stress, is a measure of the resistance that an infinite straight dislocation has to overcome when moving from one potential valley to the next. The height of this energy barrier scales with the intrinsic atomic-scale lattice distortions and thus differs profoundly in nature from the long-range stress fields imposed by dense defect populations. In other words, the friction stress describes how severely dislocations are dragged as they move through the distorted Peierls potential landscape of massive solid solutions. In that respect, multiprincipal element solid mixtures, often termed high-or medium-entropy alloys (HEAs or MEAs), provide a very promising material design basis because each individual atom experiences a set of different neighbor atoms creating high and ubiquitous local lattice distortions and stresses. [15,16] In that context, multiprincipal element face-centered cubic (fcc) alloys have the potential for achieving an outstanding yield strength-ductility ratio as they naturally carry high inherent lattice distortions. [15,17,18] However, two key challenges have not been addressed in this context so far. First, the yield strength is low due to the close packed fcc lattice structure. [19][20][21] Second, although the friction stress of these alloys is often higher than in pure metals or binary alloys, it is still usually too close to conventional structural alloys. This means that the level of lattice distortion currently exploited in most substitutional solid solution alloys does not contribute significantly to the yield strength. [20,[22][23][24][25][26][27][28] Here, based on a combined theoretical and experimental approach, we show that the degree of lattice distortion is indeed a key parameter in controlling strengthening mechanisms for the design of hitherto unexplored ultrastrong medium-entropy single-phase alloys. For this purpose, we exploit vanadium (V) as a very efficient element in a Severe lattice distortion is a core effect in the design of multiprincipal element alloys with the aim to enhance yield strength, a key indicator in structural engineering. Yet, the yield strength values of medium-and high-entropy alloys investigated so far do not substantially exceed those of conventional alloys owing to the insufficient utilization of lattice distortion. Here it is shown that a simple VCoNi equiatomic medium-entropy alloy exhibits a near 1 GP...

Although high-entropy alloys (HEAs) are attracting interest, the physical metallurgical mechanisms related to their properties have mostly not been clarified, and this limits wider industrial applications, in addition to the high alloy costs. We clarify the physical metallurgical reasons for the materials phenomena (sluggish diffusion and micro-twining at cryogenic temperatures) and investigate the effect of individual elements on solid solution hardening for the equiatomic CoCrFeMnNi HEA based on atomistic simulations (Monte Carlo, molecular dynamics and molecular statics). A significant number of stable vacant lattice sites with high migration energy barriers exists and is thought to cause the sluggish diffusion. We predict that the hexagonal close-packed (hcp) structure is more stable than the face-centered cubic (fcc) structure at 0 K, which we propose as the fundamental reason for the micro-twinning at cryogenic temperatures. The alloying effect on the critical resolved shear stress (CRSS) is well predicted by the atomistic simulation, used for a design of non-equiatomic fcc HEAs with improved strength, and is experimentally verified. This study demonstrates the applicability of the proposed atomistic approach combined with a thermodynamic calculation technique to a computational design of advanced HEAs.

No abstract

The excellent cryogenic tensile properties of the CrMnFeCoNi alloy are generally caused by deformation twinning, which is difficult to achieve at room temperature because of insufficient stress for twinning. Here, we induced twinning at room temperature to improve the cryogenic tensile properties of the CrMnFeCoNi alloy. Considering grain size effects on the critical stress for twinning, twins were readily formed in the coarse microstructure by cold rolling without grain refinement by hot rolling. These twins were retained by partial recrystallization and played an important role in improving strength, allowing yield strengths approaching 1 GPa. The persistent elongation up to 46% as well as the tensile strength of 1.3 GPa are attributed to additional twinning in both recrystallized and non-recrystallization regions. Our results demonstrate that non-recrystallized grains, which are generally avoided in conventional alloys because of their deleterious effect on ductility, can be useful in achieving high-strength high-entropy alloys.

No abstract

No abstract

No abstract

Strong and ductile materials that have high resistance to corrosion and hydrogen embrittlement are rare and yet essential for realizing safety-critical energy infrastructures, hydrogen-based industries, and transportation solutions. Here we report how we reconcile these constraints in the form of a strong and ductile CoNiV medium-entropy alloy with face-centered cubic structure. It shows high resistance to hydrogen embrittlement at ambient temperature at a strain rate of 10−4 s−1, due to its low hydrogen diffusivity and the deformation twinning that impedes crack propagation. Moreover, a dense oxide film formed on the alloy’s surface reduces the hydrogen uptake rate, and provides high corrosion resistance in dilute sulfuric acid with a corrosion current density below 7 μA cm−2. The combination of load carrying capacity and resistance to harsh environmental conditions may qualify this multi-component alloy as a potential candidate material for sustainable and safe infrastructures and devices.