Using a simple esterification reaction of a hydroxyl group with an anhydride group, pristine lignin was successfully converted to a new lignin (COOH-lignin) modified with a terminal carboxyl group. This chemical modification of pristine lignin was confirmed by the appearance of new absorption bands in the FT-IR spectrum. Then, the pristine lignin and COOH-lignin were successfully incorporated into a poly(lactic acid) (PLA) matrix by a typical melt-mixing process. When applied to the COOH-lignin, interfacial adhesion performance between the lignin filler and PLA matrix was better and stronger than pristine lignin. Based on these results for the COOH-lignin/PLA biocomposites, the cost of printing PLA 3D filaments can be reduced without changing their thermal and mechanical properties. Furthermore, the potential of lignin as a component in PLA biocomposites adequate for 3D printing was demonstrated.
High-content lignin-reinforced poly(butylene adipateco-terephthalate) (PBAT) biocomposites were successfully constructed by the incorporation of lignin particles into a biodegradable PBAT matrix. The effect of lignin content with and without a chain extender (CE) on the thermal and mechanical properties of the biocomposites was investigated. Although the mechanical properties for all biocomposites showed similar decreases with little influence from the addition of CE, the crystallization temperature increased because of the branching points of the PBAT polymer chain, which serve as heterogeneous nucleating sites for crystallization, and the nucleating effect of the lignin particle. The foamability of the lignin-reinforced PBAT biocomposites, which comprised a chemical blowing agent, azodicarbonamide, and a cross-linking agent, dicumyl peroxide, was studied. Was also studied the process in the presence of azodicarbonamide (chemical blowing agent) and dicumyl peroxide (cross-linking agent). When lignin was added to the PBAT biocomposites at a content of less than 20 wt %, a typical foam structure was detected. After the addition of CE, the lignin-reinforced PBAT biocomposites exhibited a cellular structure for lignin contents below 50 wt %. However, the foam quality of the ligninreinforced PBAT biocomposites with CE was uniform for lignin contents up to 30 wt %. This high-content lignin-reinforced PBAT biocomposite with a CE should provide cost-effective and sustainable biodegradable foam that can be used for cushioning packaging applications.
Lignin was chemically modified with oligomeric polyethylene (oPE) to form oPE-grafted lignin (oPE-g-lignin) via lignin surface acylation and a radical coupling reaction with oPE. Then, pristine lignin and oPE-g-lignin were successfully compounded with low-density polyethylene (LDPE) through a typical compounding technique. Due to the oligomeric polyethylene chains grafted to the lignin’s surface, the interfacial adhesion between the lignin particles and the LDPE matrix was considerably better in the oPE-g-lignin/LDPE biocomposite than in the pristine-lignin/LDPE one. This demonstrated that oPE-g-lignin can serve as both a biodegradable reinforcing filler, which can be loaded with a higher lignin content at 50 wt-%, and a nucleating agent to increase the crystallization temperature and improve the tensile characteristics of its LDPE biocomposites. Moreover, the foamability of the lignin-reinforced LDPE biocomposites was studied in the presence of a chemical blowing agent (azodicarbonamide) with dicumyl peroxide; for an oPE-g-lignin content up to 20 wt-%, the cell size distribution was quite uniform, and the foam expansion ratios (17.69 ± 0.92) were similar to those of the neat LDPE foam (17.04 ± 0.44).
Poly (phenylene sulfide) (PPS) is a super engineering plastic that has not only excellent rigidity and high chemical resistance but also excellent electrical insulation properties; therefore, it can be applied as an electronic cover or an overheating prevention component. This plastic has been extensively applied in the manufacture of capacitor housing as, in addition to being a functional and lightweight material, it has a safety feature that can block the electrical connection between the electrolyte inside and outside the capacitor. Moreover, the fabrication of PPS composites with high glass fiber (GF) content facilitates the development of lightweight and excellent future materials, which widens the scope of the application of this polymer. However, the crystallinity and mechanical properties of PPS/GF composites have been found to vary depending on the cooling temperature. Although extensive studies have been conducted on the influence of cooling temperature on the crystalline behavior of PPS-based composites, there has been limited research focused particularly on PPS/GF composites for capacitor housing applications. In this study, to apply PPS/GF composites as film capacitor housings, specimens were prepared via injection molding at different cooling temperatures to investigate the composites’ tensile, flexural, and impact energy absorption properties resulting in increases in mechanical properties at high cooling mold temperature. Fracture surface analysis was also performed on the fractured specimens after the impact test to confirm the orientation of the GF and the shape of the micropores. Finally, the crystallinity of the composites increased with higher cooling temperatures due to the extended crystallization time.
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