Semi-and full-interpenetrating polymer network (IPN) hydrogels composed of poly(vinyl alcohol) and polyethyleneimine (PEI) were prepared to investigate the bending behavior under the electric response. To find out the characteristics of the hydrogel in the medium, swelling ratio, and rate and water state of the hydrogels were measured. The swelling ratio of the semi-IPN hydrogels increased with PEI content in the matrix, whereas that of full-IPN hydrogels dramatically decrease with increase of PEI contents in the hydrogels. In the water state of hydrogel, the bound water and free water of semi-IPN hydrogels increased with PEI weight ratio. The full-IPN hydrogels show the lower free water content in comparison with the semi-IPN hydrogel. The IPN hydrogels exhibited bending angle change in response to external stimulus such as voltage, the bending angle increased with PEI concentration. In addition, the repeated bending behaviors according to the magnitude of the applied electric field revealed that the bending angle is reversible without collapse of formation of hydrogel in all samples. Thus, the hydrogels will be useful as novel modulation systems in the field of artificial organ and matrix for drug delivery.