A model for predicting the concentrations of leachate organics, measured as chemical oxygen demand, in groundwaters below sanitary landfill sites is developed. Simultaneous Michaelis-Menten substrate utilization and microbial mass production equations, with convection and dispersion included for the former, were used for the modeling of biodegradation. For substrate concentrations significantly less than the half utilization rate coefiScient and for microbial populations approaching a steady state the Michaelis-Menten equations are reduced to a first-order reaction kinetic model. The nonlinear model equations are solved using a Galerkin finite element technique, with a Newton Raphson iteration procedure being used to solve the resulting matrix equations. Model sensitivity studies are undertaken to determine the extent to which COD reduction might vary in the field with respect to time and space. The results indicate that substantial removal of leachate organics can be expected within short distances of the landfill even under the conditions of widely varying biological parameters. Model results are compared to the leachate organic reduction occurring below the Canadian Forces Base Borden sanitary landfill. into the adjacent soil media. As a result the potential hazard which these leachates present to groundwater quality adjacent to landfills i• apparent. Despite the strong potential for ground water pollution, comparatively little•research has been done to determine the fate of leachate organic matter in soil and to model its transport in the•groundwater system. As a result the work described in this paper was undertaken to develop a model for organic matter transport in soils adjacent to sanitary landfills and to compare model predictions with field data collected from groundwater zones below a sanitary landfill. ATTENUATION MECHANISMS Mechanisms that reduce organic matter concentrations in groundwater during movement through soil involve both •Now at INTERA Environmental Consultants, Inc., Houston, Texas 77079.,. physicochemical and biochemical processes. The most active physicochemical processes are likely to be dispersion, diffusion, and adsorption, with filtration operative for particulate matter. The biochemical processes involve microbial degradation, either aerobic or anaerobic, with the latter expected to be most active, since oxygen supply at depth within soil-groundwater systems can be expected to be limited. It has been well established that landfill leachates are anaerobically biodegradable [Foree and Reid, 1973; Boyle and Ham, 1974; Pohland, 1975; Chian and DeWalle, 1977a, b; Soyupak et al., 1978]. In addition, information is also available on the kinetics of anaerobic biodegradation of leachates from continuously stirred tank reactors [Foree and Reid, 1973; Pohland, 1975; Soyupak et al., 19•78] and soil column studies [Soyupak, 1979]. Chian and DeWnile [!977a, b] defined four distinct bio-